Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO6 (Ln = La, Nd) perovskites

M. Retuerto; M. R. Li; A. Ignatov; M. Croft; K. V. Ramanujachary; S. Chi; J. P. Hodges; W. Dachraoui; J. Hadermann; T. Thao Tran; P. Shiv Halasyamani; C. P. Grams; J. Hemberger; M. Greenblatt

doi:10.1021/ic401491y

Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO₆ (Ln = La, Nd) perovskites

M. Retuerto, M. R. Li, A. Ignatov, M. Croft, K. V. Ramanujachary, S. Chi, J. P. Hodges, W. Dachraoui, J. Hadermann, T. Thao Tran, P. Shiv Halasyamani, C. P. Grams, J. Hemberger, M. Greenblatt

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

We have expanded the double perovskite family of materials with the unusual combination of layered order in the A sublattice and rock salt order over the B sublattice to compounds NaLaFeWO₆ and NaNdFeWO₆. The materials have been synthesized and studied by powder X-ray diffraction, neutron diffraction, electron diffraction, magnetic measurements, X-ray absorption spectroscopy, dielectric measurements, and second harmonic generation. At room temperature, the crystal structures of both compounds can be defined in the noncentrosymmetric monoclinic P2₁ space group resulting from the combination of ordering both in the A and B sublattices, the distortion of the cell due to tilting of the octahedra, and the displacement of certain cations. The magnetic studies show that both compounds are ordered antiferromagnetically below T_N ≈ 25 K for NaLaFeWO₆ and at ∼21 K for NaNdFeWO₆. The magnetic structure of NaNdFeWO₆ has been solved with a propagation vector k = (¹/₂ 0 ¹/₂) as an antiferromagnetic arrangement of Fe and Nd moments. Although the samples are potential multiferroics, the dielectric measurements do not show a ferroelectric response.

Original language	English
Pages (from-to)	12482-12491
Number of pages	10
Journal	Inorganic Chemistry
Volume	52
Issue number	21
DOIs	https://doi.org/10.1021/ic401491y
State	Published - Nov 4 2013

Access to Document

10.1021/ic401491y

Cite this

Retuerto, M., Li, M. R., Ignatov, A., Croft, M., Ramanujachary, K. V., Chi, S., Hodges, J. P., Dachraoui, W., Hadermann, J., Tran, T. T., Halasyamani, P. S., Grams, C. P., Hemberger, J., & Greenblatt, M. (2013). Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO₆ (Ln = La, Nd) perovskites. Inorganic Chemistry, 52(21), 12482-12491. https://doi.org/10.1021/ic401491y

@article{17bce60404fd4a54aabe2cbc79f4ab18,

title = "Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO6 (Ln = La, Nd) perovskites",

abstract = "We have expanded the double perovskite family of materials with the unusual combination of layered order in the A sublattice and rock salt order over the B sublattice to compounds NaLaFeWO6 and NaNdFeWO6. The materials have been synthesized and studied by powder X-ray diffraction, neutron diffraction, electron diffraction, magnetic measurements, X-ray absorption spectroscopy, dielectric measurements, and second harmonic generation. At room temperature, the crystal structures of both compounds can be defined in the noncentrosymmetric monoclinic P21 space group resulting from the combination of ordering both in the A and B sublattices, the distortion of the cell due to tilting of the octahedra, and the displacement of certain cations. The magnetic studies show that both compounds are ordered antiferromagnetically below TN ≈ 25 K for NaLaFeWO6 and at ∼21 K for NaNdFeWO6. The magnetic structure of NaNdFeWO6 has been solved with a propagation vector k = (1/2 0 1/2) as an antiferromagnetic arrangement of Fe and Nd moments. Although the samples are potential multiferroics, the dielectric measurements do not show a ferroelectric response.",

author = "M. Retuerto and Li, {M. R.} and A. Ignatov and M. Croft and Ramanujachary, {K. V.} and S. Chi and Hodges, {J. P.} and W. Dachraoui and J. Hadermann and Tran, {T. Thao} and Halasyamani, {P. Shiv} and Grams, {C. P.} and J. Hemberger and M. Greenblatt",

year = "2013",

month = nov,

day = "4",

doi = "10.1021/ic401491y",

language = "English",

volume = "52",

pages = "12482--12491",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "21",

}

Retuerto, M, Li, MR, Ignatov, A, Croft, M, Ramanujachary, KV, Chi, S, Hodges, JP, Dachraoui, W, Hadermann, J, Tran, TT, Halasyamani, PS, Grams, CP, Hemberger, J & Greenblatt, M 2013, 'Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO₆ (Ln = La, Nd) perovskites', Inorganic Chemistry, vol. 52, no. 21, pp. 12482-12491. https://doi.org/10.1021/ic401491y

TY - JOUR

T1 - Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO6 (Ln = La, Nd) perovskites

AU - Retuerto, M.

AU - Li, M. R.

AU - Ignatov, A.

AU - Croft, M.

AU - Ramanujachary, K. V.

AU - Chi, S.

AU - Hodges, J. P.

AU - Dachraoui, W.

AU - Hadermann, J.

AU - Tran, T. Thao

AU - Halasyamani, P. Shiv

AU - Grams, C. P.

AU - Hemberger, J.

AU - Greenblatt, M.

PY - 2013/11/4

Y1 - 2013/11/4

N2 - We have expanded the double perovskite family of materials with the unusual combination of layered order in the A sublattice and rock salt order over the B sublattice to compounds NaLaFeWO6 and NaNdFeWO6. The materials have been synthesized and studied by powder X-ray diffraction, neutron diffraction, electron diffraction, magnetic measurements, X-ray absorption spectroscopy, dielectric measurements, and second harmonic generation. At room temperature, the crystal structures of both compounds can be defined in the noncentrosymmetric monoclinic P21 space group resulting from the combination of ordering both in the A and B sublattices, the distortion of the cell due to tilting of the octahedra, and the displacement of certain cations. The magnetic studies show that both compounds are ordered antiferromagnetically below TN ≈ 25 K for NaLaFeWO6 and at ∼21 K for NaNdFeWO6. The magnetic structure of NaNdFeWO6 has been solved with a propagation vector k = (1/2 0 1/2) as an antiferromagnetic arrangement of Fe and Nd moments. Although the samples are potential multiferroics, the dielectric measurements do not show a ferroelectric response.

AB - We have expanded the double perovskite family of materials with the unusual combination of layered order in the A sublattice and rock salt order over the B sublattice to compounds NaLaFeWO6 and NaNdFeWO6. The materials have been synthesized and studied by powder X-ray diffraction, neutron diffraction, electron diffraction, magnetic measurements, X-ray absorption spectroscopy, dielectric measurements, and second harmonic generation. At room temperature, the crystal structures of both compounds can be defined in the noncentrosymmetric monoclinic P21 space group resulting from the combination of ordering both in the A and B sublattices, the distortion of the cell due to tilting of the octahedra, and the displacement of certain cations. The magnetic studies show that both compounds are ordered antiferromagnetically below TN ≈ 25 K for NaLaFeWO6 and at ∼21 K for NaNdFeWO6. The magnetic structure of NaNdFeWO6 has been solved with a propagation vector k = (1/2 0 1/2) as an antiferromagnetic arrangement of Fe and Nd moments. Although the samples are potential multiferroics, the dielectric measurements do not show a ferroelectric response.

UR - http://www.scopus.com/inward/record.url?scp=84887094907&partnerID=8YFLogxK

U2 - 10.1021/ic401491y

DO - 10.1021/ic401491y

M3 - Article

AN - SCOPUS:84887094907

SN - 0020-1669

VL - 52

SP - 12482

EP - 12491

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 21

ER -

Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO₆ (Ln = La, Nd) perovskites

Abstract

Access to Document

Other files and links

Fingerprint

Cite this