Platinum(II) and palladium(II) complexes with 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ 5-phosphaspiro[4,4]nonane

A. V. Korostylev; O. G. Bondarev; K. A. Lyssenko; A. Yu Kovalevsky; P. V. Petrovskii; G. V. Tcherkaev; I. S. Mikhel; V. A. Davankov; K. N. Gavrilov

doi:10.1016/S0020-1693(99)00348-5

Platinum(II) and palladium(II) complexes with 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ ⁵-phosphaspiro[4,4]nonane

A. V. Korostylev
, O. G. Bondarev
, K. A. Lyssenko
, A. Yu Kovalevsky
, P. V. Petrovskii
, G. V. Tcherkaev
, I. S. Mikhel
, V. A. Davankov
, K. N. Gavrilov

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

Chelate metal complexes have been synthesised by reacting [MCODCl₂] (M = Pd, Pt) and 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ ⁵-phosphaspiro[4,4]nonane. The general formula of the products is cis-[MCl₂L], where L is a P,N-bidentate coordinated P(III) form of the initial hydrophosphorane. The structure of the products was determined by IR, ¹H, ¹³C, ¹⁴N, ¹⁵N, ³¹P, and ¹⁹⁵Pt NMR spectroscopy, plasma and laser desorption mass spectrometry, sedimentation analysis, X-ray photoelectron spectroscopy and, in the case of platinum products, by single-crystal X-ray diffraction. A tendency of the complexes to reorganise in organic solvents was revealed. In the case of the palladium complex, the process is accompanied by an increase in the degree of nuclearity.

Original language	English
Pages (from-to)	164-170
Number of pages	7
Journal	Inorganica Chimica Acta
Volume	295
Issue number	2
DOIs	https://doi.org/10.1016/S0020-1693(99)00348-5
State	Published - Nov 30 1999
Externally published	Yes

Keywords

Crystal structures
Hydrophosphoranes
P,N-ligand complexes
Palladium complexes
Platinum complexes

Access to Document

10.1016/S0020-1693(99)00348-5

Cite this

Korostylev, A. V., Bondarev, O. G., Lyssenko, K. A., Kovalevsky, A. Y., Petrovskii, P. V., Tcherkaev, G. V., Mikhel, I. S., Davankov, V. A., & Gavrilov, K. N. (1999). Platinum(II) and palladium(II) complexes with 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ ⁵-phosphaspiro[4,4]nonane. Inorganica Chimica Acta, 295(2), 164-170. https://doi.org/10.1016/S0020-1693(99)00348-5

@article{4d962e21190b40ad969283b438ce4229,

title = "Platinum(II) and palladium(II) complexes with 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ 5-phosphaspiro[4,4]nonane",

abstract = "Chelate metal complexes have been synthesised by reacting [MCODCl2] (M = Pd, Pt) and 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ 5-phosphaspiro[4,4]nonane. The general formula of the products is cis-[MCl2L], where L is a P,N-bidentate coordinated P(III) form of the initial hydrophosphorane. The structure of the products was determined by IR, 1H, 13C, 14N, 15N, 31P, and 195Pt NMR spectroscopy, plasma and laser desorption mass spectrometry, sedimentation analysis, X-ray photoelectron spectroscopy and, in the case of platinum products, by single-crystal X-ray diffraction. A tendency of the complexes to reorganise in organic solvents was revealed. In the case of the palladium complex, the process is accompanied by an increase in the degree of nuclearity.",

keywords = "Crystal structures, Hydrophosphoranes, P,N-ligand complexes, Palladium complexes, Platinum complexes",

author = "Korostylev, \{A. V.\} and Bondarev, \{O. G.\} and Lyssenko, \{K. A.\} and Kovalevsky, \{A. Yu\} and Petrovskii, \{P. V.\} and Tcherkaev, \{G. V.\} and Mikhel, \{I. S.\} and Davankov, \{V. A.\} and Gavrilov, \{K. N.\}",

year = "1999",

month = nov,

day = "30",

doi = "10.1016/S0020-1693(99)00348-5",

language = "English",

volume = "295",

pages = "164--170",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Platinum(II) and palladium(II) complexes with 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ 5-phosphaspiro[4,4]nonane

AU - Korostylev, A. V.

AU - Bondarev, O. G.

AU - Lyssenko, K. A.

AU - Kovalevsky, A. Yu

AU - Petrovskii, P. V.

AU - Tcherkaev, G. V.

AU - Mikhel, I. S.

AU - Davankov, V. A.

AU - Gavrilov, K. N.

PY - 1999/11/30

Y1 - 1999/11/30

N2 - Chelate metal complexes have been synthesised by reacting [MCODCl2] (M = Pd, Pt) and 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ 5-phosphaspiro[4,4]nonane. The general formula of the products is cis-[MCl2L], where L is a P,N-bidentate coordinated P(III) form of the initial hydrophosphorane. The structure of the products was determined by IR, 1H, 13C, 14N, 15N, 31P, and 195Pt NMR spectroscopy, plasma and laser desorption mass spectrometry, sedimentation analysis, X-ray photoelectron spectroscopy and, in the case of platinum products, by single-crystal X-ray diffraction. A tendency of the complexes to reorganise in organic solvents was revealed. In the case of the palladium complex, the process is accompanied by an increase in the degree of nuclearity.

AB - Chelate metal complexes have been synthesised by reacting [MCODCl2] (M = Pd, Pt) and 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ 5-phosphaspiro[4,4]nonane. The general formula of the products is cis-[MCl2L], where L is a P,N-bidentate coordinated P(III) form of the initial hydrophosphorane. The structure of the products was determined by IR, 1H, 13C, 14N, 15N, 31P, and 195Pt NMR spectroscopy, plasma and laser desorption mass spectrometry, sedimentation analysis, X-ray photoelectron spectroscopy and, in the case of platinum products, by single-crystal X-ray diffraction. A tendency of the complexes to reorganise in organic solvents was revealed. In the case of the palladium complex, the process is accompanied by an increase in the degree of nuclearity.

KW - Crystal structures

KW - Hydrophosphoranes

KW - P,N-ligand complexes

KW - Palladium complexes

KW - Platinum complexes

UR - https://www.scopus.com/pages/publications/0001081021

U2 - 10.1016/S0020-1693(99)00348-5

DO - 10.1016/S0020-1693(99)00348-5

M3 - Article

AN - SCOPUS:0001081021

SN - 0020-1693

VL - 295

SP - 164

EP - 170

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 2

ER -

Platinum(II) and palladium(II) complexes with 3,3,8,8-tetramethyl-1,6-dioxa-4,9-diaza-5λ ⁵-phosphaspiro[4,4]nonane

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this