Physics of grain boundaries in polycrystalline photovoltaic semiconductors

Yanfa Yan, Wan Jian Yin, Yelong Wu, Tingting Shi, Naba R. Paudel, Chen Li, Jonathan Poplawsky, Zhiwei Wang, John Moseley, Harvey Guthrey, Helio Moutinho, Stephen J. Pennycook, Mowafak M. Al-Jassim

Research output: Contribution to journalArticlepeer-review

57 Scopus citations

Abstract

Thin-film solar cells based on polycrystalline Cu(In,Ga)Se2 (CIGS) and CdTe photovoltaic semiconductors have reached remarkable laboratory efficiencies. It is surprising that these thin-film polycrystalline solar cells can reach such high efficiencies despite containing a high density of grain boundaries (GBs), which would seem likely to be nonradiative recombination centers for photo-generated carriers. In this paper, we review our atomistic theoretical understanding of the physics of grain boundaries in CIGS and CdTe absorbers. We show that intrinsic GBs with dislocation cores exhibit deep gap states in both CIGS and CdTe. However, in each solar cell device, the GBs can be chemically modified to improve their photovoltaic properties. In CIGS cells, GBs are found to be Cu-rich and contain O impurities. Density-functional theory calculations reveal that such chemical changes within GBs can remove most of the unwanted gap states. In CdTe cells, GBs are found to contain a high concentration of Cl atoms. Cl atoms donate electrons, creating n-type GBs between p-type CdTe grains, forming local p-n-p junctions along GBs. This leads to enhanced current collections. Therefore, chemical modification of GBs allows for high efficiency polycrystalline CIGS and CdTe thin-film solar cells.

Original languageEnglish
Article number112807
JournalJournal of Applied Physics
Volume117
Issue number11
DOIs
StatePublished - Mar 21 2015

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