Physics-Based Analysis of Cell Imbalances and Aging in Lithium-Ion Battery Modules and Packs

Research output: Contribution to journalArticlepeer-review

Abstract

Lithium-ion battery (LIB) packs are a key solution for grid-scale energy storage, enabling grid resilience and supporting critical infrastructure. LIB modules and packs experience current imbalances and uneven cell aging due to various design and operational factors, and require a battery management system (BMS) to continuously monitor and control. In this context, a physics-based modeling framework for LIB modules and packs (liionpack) was enhanced to identify design and control strategies that minimize current imbalance and improve module/pack operation. Simulations of an 8-cell parallel-connected module demonstrate that reducing current imbalance leads to more uniform cell aging and improved module/pack-level degradation predictions. The analysis shows that current imbalance are affected by the electrical resistances. Terminal location significantly affects imbalance, with opposite-end terminal connections at intermediate branches minimizing the imbalance, and the pack circuit construction influences the accuracy of physics-based analysis at the pack scale. This framework enables design optimization of modules and packs through a fast and easy evaluation of pack performance and aging, and supports the development of aging-informed balancing strategies compatible with BMS implementation. Thereby, offering practical pathways to improve reliability and cycle life predictions in large-scale battery energy storage systems.

Original languageEnglish
Article number080526
JournalJournal of the Electrochemical Society
Volume172
Issue number8
DOIs
StatePublished - Jul 1 2025

Funding

This material is based upon work supported by the U.S. Department of Energy, Office of Electricity (OE), Energy Storage Division and was carried out at Oak Ridge National Laboratory under Contract No. DE-AC05-00OR22725 with UT-Battelle, LLC. Also, co-authors of this article are employees of National Technology & Engineering Solutions of Sandia, LLC under Contract No. DE-NA0003525 with the U.S. Department of Energy (DOE). The authors owns all right, title and interest in and to the article and are solely responsible for its contents. The United States Government retains and the publisher, by accepting the article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. The Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan ( http://energy.gov/downloads/doe-public-access-plan ).

Keywords

  • batteries-Li-ion
  • battery pack aging
  • current imbalances
  • energy storage
  • physics based model
  • theory and modelling

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