Phason-Dominated Thermal Transport in Fresnoite

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Abstract

Fast-propagating waves in the phase of incommensurate structures, called phasons, have long been argued to enhance thermal transport. Although supersonic phason velocities have been observed, the lifetimes, from which mean free paths can be determined, have not been resolved. Using inelastic neutron scattering and thermal conductivity measurements, we establish that phasons in piezoelectric fresnoite make a major contribution to thermal conductivity by propagating with higher group velocities and longer mean free paths than phonons. The phason contribution to thermal conductivity is maximum near room temperature, where it is the single largest contributing degree of freedom.

Original languageEnglish
Article number255901
JournalPhysical Review Letters
Volume129
Issue number25
DOIs
StatePublished - Dec 16 2022

Funding

Neutron scattering by M. E. M. and R. P. H., and thermal conductivity measurements by A. F. M. were supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Materials Sciences and Engineering Division under Contract No. DE-AC05-00OR22725. This research used resources at the Spallation Neutron Source, a DOE Office of Science User Facility operated by the Oak Ridge National Laboratory.

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