Phase transitions, phase coexistence, and piezoelectric switching behavior in highly strained bifeo3 films

C. Beekman; W. Siemons; T. Z. Ward; M. Chi; J. Howe; M. D. Biegalski; N. Balke; P. Maksymovych; A. K. Farrar; J. B. Romero; P. Gao; X. Q. Pan; D. A. Tenne; H. M. Christen

doi:10.1002/adma.201302066

Phase transitions, phase coexistence, and piezoelectric switching behavior in highly strained bifeo₃ films

C. Beekman
, W. Siemons
, T. Z. Ward
, M. Chi
, J. Howe
, M. D. Biegalski
, N. Balke
, P. Maksymovych
, A. K. Farrar
, J. B. Romero
, P. Gao
, X. Q. Pan
, D. A. Tenne
, H. M. Christen

Quantum Heterostructures

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

Highly strained BiFeO₃ films transition into a true tetragonal state at 430 °C but remain polar to much higher temperatures (∼800 °C). Piezoelectric switching is only possible up to 300 °C, i.e., at temperatures for which strain stabilizes the stripe-like coexistence of multiple polymorphs.

Original language	English
Pages (from-to)	5561-5567
Number of pages	7
Journal	Advanced Materials
Volume	25
Issue number	39
DOIs	https://doi.org/10.1002/adma.201302066
State	Published - Oct 18 2013

Keywords

BiFeO
ferroelectric thin films
multiferroics
phase transitions
piezoelectric switching

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10.1002/adma.201302066

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Beekman, C., Siemons, W., Ward, T. Z., Chi, M., Howe, J., Biegalski, M. D., Balke, N., Maksymovych, P., Farrar, A. K., Romero, J. B., Gao, P., Pan, X. Q., Tenne, D. A., & Christen, H. M. (2013). Phase transitions, phase coexistence, and piezoelectric switching behavior in highly strained bifeo₃ films. Advanced Materials, 25(39), 5561-5567. https://doi.org/10.1002/adma.201302066

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title = "Phase transitions, phase coexistence, and piezoelectric switching behavior in highly strained bifeo3 films",

abstract = "Highly strained BiFeO3 films transition into a true tetragonal state at 430 °C but remain polar to much higher temperatures (∼800 °C). Piezoelectric switching is only possible up to 300 °C, i.e., at temperatures for which strain stabilizes the stripe-like coexistence of multiple polymorphs.",

keywords = "BiFeO, ferroelectric thin films, multiferroics, phase transitions, piezoelectric switching",

author = "C. Beekman and W. Siemons and Ward, \{T. Z.\} and M. Chi and J. Howe and Biegalski, \{M. D.\} and N. Balke and P. Maksymovych and Farrar, \{A. K.\} and Romero, \{J. B.\} and P. Gao and Pan, \{X. Q.\} and Tenne, \{D. A.\} and Christen, \{H. M.\}",

year = "2013",

month = oct,

day = "18",

doi = "10.1002/adma.201302066",

language = "English",

volume = "25",

pages = "5561--5567",

journal = "Advanced Materials",

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TY - JOUR

T1 - Phase transitions, phase coexistence, and piezoelectric switching behavior in highly strained bifeo3 films

AU - Beekman, C.

AU - Siemons, W.

AU - Ward, T. Z.

AU - Chi, M.

AU - Howe, J.

AU - Biegalski, M. D.

AU - Balke, N.

AU - Maksymovych, P.

AU - Farrar, A. K.

AU - Romero, J. B.

AU - Gao, P.

AU - Pan, X. Q.

AU - Tenne, D. A.

AU - Christen, H. M.

PY - 2013/10/18

Y1 - 2013/10/18

N2 - Highly strained BiFeO3 films transition into a true tetragonal state at 430 °C but remain polar to much higher temperatures (∼800 °C). Piezoelectric switching is only possible up to 300 °C, i.e., at temperatures for which strain stabilizes the stripe-like coexistence of multiple polymorphs.

AB - Highly strained BiFeO3 films transition into a true tetragonal state at 430 °C but remain polar to much higher temperatures (∼800 °C). Piezoelectric switching is only possible up to 300 °C, i.e., at temperatures for which strain stabilizes the stripe-like coexistence of multiple polymorphs.

KW - BiFeO

KW - ferroelectric thin films

KW - multiferroics

KW - phase transitions

KW - piezoelectric switching

UR - https://www.scopus.com/pages/publications/84886245554

U2 - 10.1002/adma.201302066

DO - 10.1002/adma.201302066

M3 - Article

AN - SCOPUS:84886245554

SN - 0935-9648

VL - 25

SP - 5561

EP - 5567

JO - Advanced Materials

JF - Advanced Materials

IS - 39

ER -

Phase transitions, phase coexistence, and piezoelectric switching behavior in highly strained bifeo₃ films

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Keywords

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