Phase morphology and molecular dynamics of a polyurethane ionomer reinforced with a liquid crystalline filler

A. G. Charnetskaya, G. Polizos, V. I. Shtompel, E. G. Privalko, Yu Yu Kercha, P. Pissis

Research output: Contribution to journalArticlepeer-review

25 Scopus citations

Abstract

Solution-blended binary composites of ionic segmented polyurethane (SPU-I) and liquid crystalline oligomer (LCO) were characterized by wide-angle (WAXS) and small-angle (SAXS) X-ray scattering, differential scanning calorimetry (DSC), thermally stimulated depolarization currents (TSDC) and dielectric relaxation spectroscopy (DRS). Both components mutually influenced their states of aggregation in blends (most significantly, promoting smearing-out of interfaces between stiff and soft chain fragments of SPU-I into broad interfacial regions of intermediate composition). Apparently, the blend with w=0.10 happened to be most favorable for crystallization of the LCO, while the degree of microphase separation for SPU-I became lower and the distribution of stiff domains by sizes became broader, the higher the LCO content. The overall molecular mobility of SPU-I in blends was significantly reduced. This reduction included the intensity of the secondary and the primary relaxations, and of the interfacial Maxwell-Wagner-Sillars (MWS) relaxation, whereas the transition temperatures remained essentially composition-invariant. The Arrhenius-like behavior for the dc conductivity concomitant to the non-Arrhenius (i.e., Vogel-Tammann-Fulcher) frequency dependence for the α relaxation in blends suggested a decoupling of conductivity from the motion of the SPU-I soft chain segments.

Original languageEnglish
Pages (from-to)2167-2174
Number of pages8
JournalEuropean Polymer Journal
Volume39
Issue number11
DOIs
StatePublished - Nov 2003
Externally publishedYes

Keywords

  • Dielectric relaxation
  • Liquid crystalline/polyurethane ionomer composties
  • Microphase separation
  • Molecular mobility

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