Abstract
High-resolution powder neutron diffraction has been used to study the crystal structure of the Mg11B2 superconductor (Tc = 39.2 K) prepared at high pressure in the temperature range 2 to 293 K. The experimental data provide clear evidence of temperature-independent phase inhomogeneity, which was modelled by coexisting Mg1+δB2 phases. Precise structural information for temperatures near Tc also reveals extremely small volume and c-axis discontinuities, consistent with the existence of a specific heat anomaly at Tc.
Original language | English |
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Pages (from-to) | L795-L802 |
Journal | Journal of Physics Condensed Matter |
Volume | 13 |
Issue number | 35 |
DOIs | |
State | Published - Sep 3 2001 |
Externally published | Yes |