PET-RAFT polymerization under flow chemistry and surface-initiated reactions

Li Han Rong; Eugene B. Caldona; Rigoberto C. Advincula

doi:10.1002/pi.6475

PET-RAFT polymerization under flow chemistry and surface-initiated reactions

Li Han Rong, Eugene B. Caldona, Rigoberto C. Advincula

Macromolecular Nanomaterials

Research output: Contribution to journal › Short survey › peer-review

11 Scopus citations

Abstract

Recently, photoinduced electron/energy transfer reversible addition–fragmentation chain transfer (PET-RAFT) polymerization has been developed and gaining wide acceptance. PET-RAFT polymerization uses visible light to initiate the reaction and is compatible with ambient conditions and green solvents. It also maintains the ability to produce well-defined polymers and possesses high potential as an alternative to the conventional RAFT technique. This review aims to summarize the fundamentals of PET-RAFT polymerization, highlight two of the most commonly studied applications of PET-RAFT process (i.e. flow chemistry and surface-initiated polymerization), and explore perspectives and new possibilities of the technique.

Original language	English
Pages (from-to)	145-157
Number of pages	13
Journal	Polymer International
Volume	72
Issue number	2
DOIs	https://doi.org/10.1002/pi.6475
State	Published - Feb 2023

Funding

We gratefully acknowledge technical support from Malvern Panalytical, Frontier Laboratories, and Quantum Analytics. Work (or part of this work) by R.C.Advincula was conducted using resources from ORNL's Center for Nanophase Materials Sciences (RCA), a US Department of Energy Office of Science User Facility.

Funders	Funder number
ORNL's Center for Nanophase Materials Sciences
Office of Science
Royal College of Art

Keywords

PET-RAFT
flow chemistry
polymer brushes
surface-initiated

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10.1002/pi.6475

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title = "PET-RAFT polymerization under flow chemistry and surface-initiated reactions",

abstract = "Recently, photoinduced electron/energy transfer reversible addition–fragmentation chain transfer (PET-RAFT) polymerization has been developed and gaining wide acceptance. PET-RAFT polymerization uses visible light to initiate the reaction and is compatible with ambient conditions and green solvents. It also maintains the ability to produce well-defined polymers and possesses high potential as an alternative to the conventional RAFT technique. This review aims to summarize the fundamentals of PET-RAFT polymerization, highlight two of the most commonly studied applications of PET-RAFT process (i.e. flow chemistry and surface-initiated polymerization), and explore perspectives and new possibilities of the technique.",

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author = "Rong, {Li Han} and Caldona, {Eugene B.} and Advincula, {Rigoberto C.}",

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year = "2023",

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T1 - PET-RAFT polymerization under flow chemistry and surface-initiated reactions

AU - Rong, Li Han

AU - Caldona, Eugene B.

AU - Advincula, Rigoberto C.

PY - 2023/2

Y1 - 2023/2

N2 - Recently, photoinduced electron/energy transfer reversible addition–fragmentation chain transfer (PET-RAFT) polymerization has been developed and gaining wide acceptance. PET-RAFT polymerization uses visible light to initiate the reaction and is compatible with ambient conditions and green solvents. It also maintains the ability to produce well-defined polymers and possesses high potential as an alternative to the conventional RAFT technique. This review aims to summarize the fundamentals of PET-RAFT polymerization, highlight two of the most commonly studied applications of PET-RAFT process (i.e. flow chemistry and surface-initiated polymerization), and explore perspectives and new possibilities of the technique.

AB - Recently, photoinduced electron/energy transfer reversible addition–fragmentation chain transfer (PET-RAFT) polymerization has been developed and gaining wide acceptance. PET-RAFT polymerization uses visible light to initiate the reaction and is compatible with ambient conditions and green solvents. It also maintains the ability to produce well-defined polymers and possesses high potential as an alternative to the conventional RAFT technique. This review aims to summarize the fundamentals of PET-RAFT polymerization, highlight two of the most commonly studied applications of PET-RAFT process (i.e. flow chemistry and surface-initiated polymerization), and explore perspectives and new possibilities of the technique.

KW - PET-RAFT

KW - flow chemistry

KW - polymer brushes

KW - surface-initiated

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SN - 0959-8103

VL - 72

SP - 145

EP - 157

JO - Polymer International

JF - Polymer International

IS - 2

ER -

PET-RAFT polymerization under flow chemistry and surface-initiated reactions

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