Perovskite-related ZrO2-doped SrCo0.4Fe0.6O3-δ membrane for oxygen permeation

Shiguang Li; Wanqin Jin; Pei Huang; Nanping Xu; Jun Shi; Michael Z.C. Hu; E. Andrew Payzant; Y. H. Ma

doi:10.1002/aic.690450208

Perovskite-related ZrO₂-doped SrCo_0.4Fe_0.6O_3-δ membrane for oxygen permeation

Shiguang Li, Wanqin Jin, Pei Huang, Nanping Xu, Jun Shi, Michael Z.C. Hu, E. Andrew Payzant, Y. H. Ma

Materials Engineering

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

A typicalperouskite La_0.2Sr_0.8Co_0.2Fe_0.8O _3-δ (LSCF) membrane and a novel perovskite-related ZrO₂-doped SrCo_0.4Fe_0.6O_3-δ (SCFZ) membrane were successfully prepared. The sintered membranes were characterized by an in-situ high-temperature X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. Oxygen permeabilities of the two dense membranes were measured in the temperature range of 923 to 1,173 K under a fixed oxygen partial pressure gradient. The results of the oxygen permeation experiment and high-temperature X-ray diffraction in argon atmosphere indicate that the perovskite-related SCFZ membrane has higher oxygen fluxes and is stable than that of the LSCF membrane at elevated temperatures and reduced oxygen partial pressures.

Original language	English
Pages (from-to)	276-284
Number of pages	9
Journal	AIChE Journal
Volume	45
Issue number	2
DOIs	https://doi.org/10.1002/aic.690450208
State	Published - Feb 1999

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@article{27cb187e3f954484aeb81785c9800962,

title = "Perovskite-related ZrO2-doped SrCo0.4Fe0.6O3-δ membrane for oxygen permeation",

abstract = "A typicalperouskite La0.2Sr0.8Co0.2Fe0.8O 3-δ (LSCF) membrane and a novel perovskite-related ZrO2-doped SrCo0.4Fe0.6O3-δ (SCFZ) membrane were successfully prepared. The sintered membranes were characterized by an in-situ high-temperature X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. Oxygen permeabilities of the two dense membranes were measured in the temperature range of 923 to 1,173 K under a fixed oxygen partial pressure gradient. The results of the oxygen permeation experiment and high-temperature X-ray diffraction in argon atmosphere indicate that the perovskite-related SCFZ membrane has higher oxygen fluxes and is stable than that of the LSCF membrane at elevated temperatures and reduced oxygen partial pressures.",

author = "Shiguang Li and Wanqin Jin and Pei Huang and Nanping Xu and Jun Shi and Hu, {Michael Z.C.} and Payzant, {E. Andrew} and Ma, {Y. H.}",

year = "1999",

month = feb,

doi = "10.1002/aic.690450208",

language = "English",

volume = "45",

pages = "276--284",

journal = "AIChE Journal",

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T1 - Perovskite-related ZrO2-doped SrCo0.4Fe0.6O3-δ membrane for oxygen permeation

AU - Li, Shiguang

AU - Jin, Wanqin

AU - Huang, Pei

AU - Xu, Nanping

AU - Shi, Jun

AU - Hu, Michael Z.C.

AU - Payzant, E. Andrew

AU - Ma, Y. H.

PY - 1999/2

Y1 - 1999/2

N2 - A typicalperouskite La0.2Sr0.8Co0.2Fe0.8O 3-δ (LSCF) membrane and a novel perovskite-related ZrO2-doped SrCo0.4Fe0.6O3-δ (SCFZ) membrane were successfully prepared. The sintered membranes were characterized by an in-situ high-temperature X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. Oxygen permeabilities of the two dense membranes were measured in the temperature range of 923 to 1,173 K under a fixed oxygen partial pressure gradient. The results of the oxygen permeation experiment and high-temperature X-ray diffraction in argon atmosphere indicate that the perovskite-related SCFZ membrane has higher oxygen fluxes and is stable than that of the LSCF membrane at elevated temperatures and reduced oxygen partial pressures.

AB - A typicalperouskite La0.2Sr0.8Co0.2Fe0.8O 3-δ (LSCF) membrane and a novel perovskite-related ZrO2-doped SrCo0.4Fe0.6O3-δ (SCFZ) membrane were successfully prepared. The sintered membranes were characterized by an in-situ high-temperature X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. Oxygen permeabilities of the two dense membranes were measured in the temperature range of 923 to 1,173 K under a fixed oxygen partial pressure gradient. The results of the oxygen permeation experiment and high-temperature X-ray diffraction in argon atmosphere indicate that the perovskite-related SCFZ membrane has higher oxygen fluxes and is stable than that of the LSCF membrane at elevated temperatures and reduced oxygen partial pressures.

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U2 - 10.1002/aic.690450208

DO - 10.1002/aic.690450208

M3 - Article

AN - SCOPUS:0033083912

SN - 0001-1541

VL - 45

SP - 276

EP - 284

JO - AIChE Journal

JF - AIChE Journal

IS - 2

ER -

Perovskite-related ZrO₂-doped SrCo_0.4Fe_0.6O_3-δ membrane for oxygen permeation

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