Abstract
Here we report a facile synthesis of Pd@Rh core-shell nanocrystals with octahedral and cubic shapes. Under optimized conditions, Rh atoms can be deposited on Pd octahedral or cubic seeds in a layer-by-layer fashion to generate core-shell nanocrystals with a well-controlled shape. We then use CO oxidation as a probe to evaluate the catalytic performance of the core-shell nanocrystals with reference to a number of commercial catalysts. When supported on mesoporous silica, both the octahedral and cubic Pd@Rh nanocrystals show CO to CO2 conversion levels similar to that of a commercial Pt/Al2O3 catalyst while the two catalysts based on pure Rh (commercial Rh/C and Rh nanocubes/silica) needed much higher temperatures to reach the same level of conversion. In terms of ignition temperature, the Rh nanocubes show a value of 260 °C while those of the octahedral and cubic Pd@Rh nanocrystals are as low as 140 and 150 °C, respectively. Our results suggest that there is no significant difference between the octahedral and cubic Pd@Rh nanocrystals in terms of performance towards CO oxidation while both of them are advantageous over Rh nanocubes or Rh/C.
| Original language | English |
|---|---|
| Pages (from-to) | 1232-1238 |
| Number of pages | 7 |
| Journal | Nanoscale Horizons |
| Volume | 4 |
| Issue number | 5 |
| DOIs | |
| State | Published - Sep 2019 |
Funding
This work was supported by start-up funds from the Georgia Institute of Technology. S.-I. C. was partially supported by the National Research Foundation (NRF) of Korea under grant no. NRF2018R1C1B6004272.