Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid

Alberto Villa; Marco Schiavoni; Sebastiano Campisi; Gabriel M. Veith; Laura Prati

doi:10.1002/cssc.201200778

Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid

Alberto Villa, Marco Schiavoni, Sebastiano Campisi, Gabriel M. Veith, Laura Prati

Energy Storage & Conversion

Research output: Contribution to journal › Article › peer-review

223 Scopus citations

Abstract

Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA.

Original language	English
Pages (from-to)	609-612
Number of pages	4
Journal	ChemSusChem
Volume	6
Issue number	4
DOIs	https://doi.org/10.1002/cssc.201200778
State	Published - Apr 2013

Keywords

Alloys
Gold
Hydroxymethylfurfural
Oxidation
Palladium

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10.1002/cssc.201200778

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abstract = "Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA.",

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author = "Alberto Villa and Marco Schiavoni and Sebastiano Campisi and Veith, {Gabriel M.} and Laura Prati",

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AU - Villa, Alberto

AU - Schiavoni, Marco

AU - Campisi, Sebastiano

AU - Veith, Gabriel M.

AU - Prati, Laura

PY - 2013/4

Y1 - 2013/4

N2 - Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA.

AB - Mixed noblility: We show that the modification of a gold/carbon catalyst with platinum or palladium produces stable and recyclable catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA): the support and nanoparticle chemistry directly mediate the selective oxidation of terminal hydroxyl groups in bio-derived HMF. This finding is a significant advance over current conversion technology because of the technological importance of FDCA.

KW - Alloys

KW - Gold

KW - Hydroxymethylfurfural

KW - Oxidation

KW - Palladium

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ER -

Pd-modified Au on carbon as an effective and durable catalyst for the direct oxidation of HMF to 2,5-furandicarboxylic acid

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Keywords

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