Oxidation resistance: One barrier to moving beyond Ni-base superalloys

B. A. Pint, J. R. DiStefano, I. G. Wright

Research output: Contribution to journalArticlepeer-review

128 Scopus citations

Abstract

The implementation of new high-temperature materials is often hampered by their lack of oxidation or environmental resistance. This failing is one of the strongest barriers to moving beyond Ni-base superalloys for many commercial applications. In practice, usable high-temperature alloys have at least reasonable oxidation resistance, but the current generation of single-crystal Ni-base superalloys has sufficient oxidation resistance that optimized versions can be used without a metallic bond coating and only an oxygen-transparent ceramic coating for thermal protection. The material development process often centers around mechanical properties, while oxidation resistance, along with other realities, is given minor attention. For many applications, the assumption that an oxidation-resistant coating can be used to protect a substrate is seriously flawed, as coatings often do not provide sufficient reliability for critical components. Examples of oxidation problems are given for currently used materials and materials classes with critical oxidation resistance problems.

Original languageEnglish
Pages (from-to)255-263
Number of pages9
JournalMaterials Science and Engineering: A
Volume415
Issue number1-2
DOIs
StatePublished - Jan 15 2006

Funding

This research was sponsored by the U.S. Department of Energy, Fossil Energy Advanced Research Materials Program and the Advanced Turbine Systems Program under Contract DE-AC05-00OR22725 with UT-Battelle, LLC. Peter Tortorelli and Mike Brady at ORNL and Roger Reed from Imperial College, London provided comments on the manuscript.

FundersFunder number
U.S. Department of Energy
Office of Fossil EnergyDE-AC05-00OR22725

    Keywords

    • Coatings
    • Oxidation resistance
    • Refractory metals
    • Superalloys

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