Oxidation of accident tolerant fuel candidates

In this study, the oxidation of various accident tolerant fuel candidates produced under different conditions have been evaluated and compared relative to the reference standard–UO₂. The candidates considered in this study were UN, U₃Si₂, U₃Si₅, and a composite material composed of UN–U₃Si₂. With the spark plasma sintering (SPS) method, it was possible to fabricate samples of UN with varying porosity, as well as a high-density composite of UN–U₃Si₂ (10%). Using thermogravimetry in air, the oxidation behaviors of each material and the various microstructures of UN were assessed. These results reveal that it is possible to fabricate UN to very high densities using the SPS method, such that its resistance to oxidation can be improved compared to U₃Si₅ and UO₂, and compete favorably with the principal ATF candidates, U₃Si₂, which shows a particularly violent reaction under the conditions of this study, and the UN–U₃Si₂ (10%) composite.