Oxidation and crystallization of Zr-based bulk metallic glass due to machining

Mustafa Bakkal, Chain T. Liu, Thomas R. Watkins, Ronald O. Scattergood, Albert J. Shih

Research output: Contribution to journalArticlepeer-review

88 Scopus citations

Abstract

Bulk metallic glass was subjected to extreme deformation conditions during machining operation. The flash temperature, oxidation and crystallization within chips from a Zr-based bulk metallic glass were investigated. A near-infrared spectrometer was used to capture the light emission from the tool-chip interface allowing the calculation of the temperature. Very high temperatures in the 2400-2700 K range were observed and associated with the light emission and oxidation in the chips. X-ray diffraction analysis revealed oxidation of chips machined at high cutting speeds. Optical micrographs of polished and etched chip cross-sections showed a dendritic pattern due to crystallization. Using a field emission gun SEM, amorphous and crystalline regions were analyzed. This study demonstrates the oxidation and crystallization of bulk metallic glass during machining.

Original languageEnglish
Pages (from-to)195-204
Number of pages10
JournalIntermetallics
Volume12
Issue number2
DOIs
StatePublished - Feb 2004

Funding

The authors would like to thank Dr. Edgar Lara-Curzio for helpful suggestions. This research is partially sponsored the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Transportation Technologies, as part of the High Temperature Materials Laboratory User Program, Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the US Dept. of Energy under contract DE-AC05-00OR22725.

FundersFunder number
Office of Transportation Technologies
U.S. Department of EnergyDE-AC05-00OR22725
Office of Energy Efficiency and Renewable Energy
Oak Ridge National Laboratory

    Keywords

    • B. Metallic glasses
    • B. Oxidation
    • C. Machining
    • F. Scanning
    • F. X-ray diffraction

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