Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature

D. N. Voylov; I. N. Ivanov; V. I. Bykov; S. B. Tsybenova; I. A. Merkulov; S. A. Kurochkin; A. P. Holt; A. M. Kisliuk; A. P. Sokolov

doi:10.1039/c6ra14414d

Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature

D. N. Voylov, I. N. Ivanov, V. I. Bykov, S. B. Tsybenova, I. A. Merkulov, S. A. Kurochkin, A. P. Holt, A. M. Kisliuk, A. P. Sokolov

Soft Materials and Membranes

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4 Scopus citations

Abstract

We report the observation of oscillatory redox reactions on the surface of multilayer graphene oxide (GO) films at room temperature. The redox reactions exhibited dampened oscillatory behavior with a period of about 5 days and were found to be dependent on the time elapsed from film deposition. The kinetic behavior observed for the oxidation-reduction reactions and the metastability of the surface functional groups are adequately described by two models involving GO reactions and reactant diffusion.

Original language	English
Pages (from-to)	78194-78201
Number of pages	8
Journal	RSC Advances
Volume	6
Issue number	81
DOIs	https://doi.org/10.1039/c6ra14414d
State	Published - 2016

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title = "Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature",

abstract = "We report the observation of oscillatory redox reactions on the surface of multilayer graphene oxide (GO) films at room temperature. The redox reactions exhibited dampened oscillatory behavior with a period of about 5 days and were found to be dependent on the time elapsed from film deposition. The kinetic behavior observed for the oxidation-reduction reactions and the metastability of the surface functional groups are adequately described by two models involving GO reactions and reactant diffusion.",

author = "Voylov, {D. N.} and Ivanov, {I. N.} and Bykov, {V. I.} and Tsybenova, {S. B.} and Merkulov, {I. A.} and Kurochkin, {S. A.} and Holt, {A. P.} and Kisliuk, {A. M.} and Sokolov, {A. P.}",

note = "Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6ra14414d",

language = "English",

volume = "6",

pages = "78194--78201",

journal = "RSC Advances",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature

AU - Voylov, D. N.

AU - Ivanov, I. N.

AU - Bykov, V. I.

AU - Tsybenova, S. B.

AU - Merkulov, I. A.

AU - Kurochkin, S. A.

AU - Holt, A. P.

AU - Kisliuk, A. M.

AU - Sokolov, A. P.

PY - 2016

Y1 - 2016

N2 - We report the observation of oscillatory redox reactions on the surface of multilayer graphene oxide (GO) films at room temperature. The redox reactions exhibited dampened oscillatory behavior with a period of about 5 days and were found to be dependent on the time elapsed from film deposition. The kinetic behavior observed for the oxidation-reduction reactions and the metastability of the surface functional groups are adequately described by two models involving GO reactions and reactant diffusion.

AB - We report the observation of oscillatory redox reactions on the surface of multilayer graphene oxide (GO) films at room temperature. The redox reactions exhibited dampened oscillatory behavior with a period of about 5 days and were found to be dependent on the time elapsed from film deposition. The kinetic behavior observed for the oxidation-reduction reactions and the metastability of the surface functional groups are adequately described by two models involving GO reactions and reactant diffusion.

UR - http://www.scopus.com/inward/record.url?scp=85029469432&partnerID=8YFLogxK

U2 - 10.1039/c6ra14414d

DO - 10.1039/c6ra14414d

M3 - Article

AN - SCOPUS:85029469432

SN - 2046-2069

VL - 6

SP - 78194

EP - 78201

JO - RSC Advances

JF - RSC Advances

IS - 81

ER -

Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature

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