Order in vertically aligned carbon nanotube arrays

H. Wang, Z. Xu, G. Eres

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Abstract

We report the direct measurements on the bulk morphology of vertically aligned multiwalled carbon nanotube (CNT) arrays using small angle neutron scattering (SANS). SANS measurements at different heights of CNT arrays corresponding to different stages of the growth reveal increasing alignment order along the thickness and two distinctly different CNT morphologies. The observations suggest that the evolution of the macroscopic CNT morphologies be driven by competing collective growth and spatial constraints.

Original languageEnglish
Article number213111
JournalApplied Physics Letters
Volume88
Issue number21
DOIs
StatePublished - May 21 2006

Funding

One of the authors (H.W.) acknowledges the NSF Career Award DMR-0348895 and the support of the National Institute of Standards and Technology in providing the neutron research facilities used in this work. Another author (G.E.) is supported by the Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under Contract No. DE-AC05-00OR22725 and the Laboratory-Directed Research and Development Program at ORNL. Part of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Division of Scientific User Facilities, U.S. Department of Energy.

FundersFunder number
Laboratory-Directed Research and Development Program
National Science FoundationDMR-0348895
U.S. Department of EnergyDE-AC05-00OR22725
National Institute of Standards and Technology
Basic Energy Sciences
Oak Ridge National Laboratory

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