Optimized parameters for synthesis of BaTiO3 films with high electromechanical coupling

Zhi Zhou; Christopher C. Bowland; Brendan A. Patterson; Mohammad H. Malakooti; Henry A. Sodano

doi:10.1115/SMASIS2016-9126

Optimized parameters for synthesis of BaTiO₃ films with high electromechanical coupling

Zhi Zhou
, Christopher C. Bowland
, Brendan A. Patterson
, Mohammad H. Malakooti
, Henry A. Sodano

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

This research improves upon prior research efforts on the hydrothermal synthesis of barium titanate (BaTiO₃) films. It has been established that BaTiO₃ can be synthesized using a two-step hydrothermal reaction that first synthesizes TiO₂ then converts it to BaTiO₃. Past research, however, resulted in relatively low ferroelectric properties using this technique. The research addresses that shortcoming by offering an optimized hydrothermal synthesis process that significantly increase the electromechanical coupling of the BaTiO₃ film. Here, it is shown that the d₃₃ achieves a value of 80 pm/V, which is the bulk BaTiO₃ value. Additionally, this optimization results in an enhanced dielectric constant of 1600. Therefore, this research reveals that the ferroelectric properties of a hydrothermally synthesized BaTiO₃ film can be significantly enhanced through slight modifications in the hydrothermal processing procedure.

Original language	English
Title of host publication	Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring
Publisher	American Society of Mechanical Engineers
ISBN (Electronic)	9780791850480
DOIs	https://doi.org/10.1115/SMASIS2016-9126
State	Published - 2016
Externally published	Yes
Event	ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016 - Stowe, United States Duration: Sep 28 2016 → Sep 30 2016

Publication series

Name	ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016
Volume	1

Conference

Conference	ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016
Country/Territory	United States
City	Stowe
Period	09/28/16 → 09/30/16

Access to Document

10.1115/SMASIS2016-9126

Cite this

Zhou, Z., Bowland, C. C., Patterson, B. A., Malakooti, M. H., & Sodano, H. A. (2016). Optimized parameters for synthesis of BaTiO₃ films with high electromechanical coupling. In Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring Article V001T01A008 (ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016; Vol. 1). American Society of Mechanical Engineers. https://doi.org/10.1115/SMASIS2016-9126

Zhou, Zhi ; Bowland, Christopher C. ; Patterson, Brendan A. et al. / Optimized parameters for synthesis of BaTiO₃ films with high electromechanical coupling. Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring. American Society of Mechanical Engineers, 2016. (ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016).

@inproceedings{64589171199a4577867a7d7d981d4bbe,

title = "Optimized parameters for synthesis of BaTiO3 films with high electromechanical coupling",

abstract = "This research improves upon prior research efforts on the hydrothermal synthesis of barium titanate (BaTiO3) films. It has been established that BaTiO3 can be synthesized using a two-step hydrothermal reaction that first synthesizes TiO2 then converts it to BaTiO3. Past research, however, resulted in relatively low ferroelectric properties using this technique. The research addresses that shortcoming by offering an optimized hydrothermal synthesis process that significantly increase the electromechanical coupling of the BaTiO3 film. Here, it is shown that the d33 achieves a value of 80 pm/V, which is the bulk BaTiO3 value. Additionally, this optimization results in an enhanced dielectric constant of 1600. Therefore, this research reveals that the ferroelectric properties of a hydrothermally synthesized BaTiO3 film can be significantly enhanced through slight modifications in the hydrothermal processing procedure.",

author = "Zhi Zhou and Bowland, \{Christopher C.\} and Patterson, \{Brendan A.\} and Malakooti, \{Mohammad H.\} and Sodano, \{Henry A.\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2016 by ASME.; ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016 ; Conference date: 28-09-2016 Through 30-09-2016",

year = "2016",

doi = "10.1115/SMASIS2016-9126",

language = "English",

series = "ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016",

publisher = "American Society of Mechanical Engineers",

booktitle = "Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring",

}

Zhou, Z, Bowland, CC, Patterson, BA, Malakooti, MH & Sodano, HA 2016, Optimized parameters for synthesis of BaTiO₃ films with high electromechanical coupling. in Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring., V001T01A008, ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016, vol. 1, American Society of Mechanical Engineers, ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016, Stowe, United States, 09/28/16. https://doi.org/10.1115/SMASIS2016-9126

Optimized parameters for synthesis of BaTiO₃ films with high electromechanical coupling. / Zhou, Zhi; Bowland, Christopher C.; Patterson, Brendan A. et al.
Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring. American Society of Mechanical Engineers, 2016. V001T01A008 (ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016; Vol. 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

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AU - Bowland, Christopher C.

AU - Patterson, Brendan A.

AU - Malakooti, Mohammad H.

AU - Sodano, Henry A.

PY - 2016

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N2 - This research improves upon prior research efforts on the hydrothermal synthesis of barium titanate (BaTiO3) films. It has been established that BaTiO3 can be synthesized using a two-step hydrothermal reaction that first synthesizes TiO2 then converts it to BaTiO3. Past research, however, resulted in relatively low ferroelectric properties using this technique. The research addresses that shortcoming by offering an optimized hydrothermal synthesis process that significantly increase the electromechanical coupling of the BaTiO3 film. Here, it is shown that the d33 achieves a value of 80 pm/V, which is the bulk BaTiO3 value. Additionally, this optimization results in an enhanced dielectric constant of 1600. Therefore, this research reveals that the ferroelectric properties of a hydrothermally synthesized BaTiO3 film can be significantly enhanced through slight modifications in the hydrothermal processing procedure.

AB - This research improves upon prior research efforts on the hydrothermal synthesis of barium titanate (BaTiO3) films. It has been established that BaTiO3 can be synthesized using a two-step hydrothermal reaction that first synthesizes TiO2 then converts it to BaTiO3. Past research, however, resulted in relatively low ferroelectric properties using this technique. The research addresses that shortcoming by offering an optimized hydrothermal synthesis process that significantly increase the electromechanical coupling of the BaTiO3 film. Here, it is shown that the d33 achieves a value of 80 pm/V, which is the bulk BaTiO3 value. Additionally, this optimization results in an enhanced dielectric constant of 1600. Therefore, this research reveals that the ferroelectric properties of a hydrothermally synthesized BaTiO3 film can be significantly enhanced through slight modifications in the hydrothermal processing procedure.

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BT - Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring

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Zhou Z, Bowland CC, Patterson BA, Malakooti MH, Sodano HA. Optimized parameters for synthesis of BaTiO₃ films with high electromechanical coupling. In Multifunctional Materials; Mechanics and Behavior of Active Materials; Integrated System Design and Implementation; Structural Health Monitoring. American Society of Mechanical Engineers. 2016. V001T01A008. (ASME 2016 Conference on Smart Materials, Adaptive Structures and Intelligent Systems, SMASIS 2016). doi: 10.1115/SMASIS2016-9126