One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium(4+) Complex

Kyle Fulle; Liurukara D. Sanjeewa; Colin D. McMillen; Yimei Wen; Apeksha C. Rajamanthrilage; Jeffrey N. Anker; George Chumanov; Joseph W. Kolis

doi:10.1021/acs.inorgchem.7b00821

One-Pot Hydrothermal Synthesis of Tb^III₁₃(GeO₄)₆O₇(OH) and K₂Tb^IVGe₂O₇: Preparation of a Stable Terbium(4+) Complex

Kyle Fulle
, Liurukara D. Sanjeewa
, Colin D. McMillen
, Yimei Wen
, Apeksha C. Rajamanthrilage
, Jeffrey N. Anker
, George Chumanov
, Joseph W. Kolis

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb₄O₇ as a starting material. Tb₁₃(GeO₄)₆O₇(OH) crystallizes in trigonal space group R3̅, is built up of isolated GeO₄ units, and contains a complex arrangement of terbium oxide polyhedra. K₂TbGe₂O₇ is a terbium(4+) pyrogermanate that is isostructural with K₂ZrGe₂O₇ and displays a rare stable Tb⁴⁺ oxidation state in the solid state.

Original language	English
Pages (from-to)	6044-6047
Number of pages	4
Journal	Inorganic Chemistry
Volume	56
Issue number	11
DOIs	https://doi.org/10.1021/acs.inorgchem.7b00821
State	Published - Jun 5 2017
Externally published	Yes

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10.1021/acs.inorgchem.7b00821

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title = "One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7: Preparation of a Stable Terbium(4+) Complex",

abstract = "Two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R3̅, is built up of isolated GeO4 units, and contains a complex arrangement of terbium oxide polyhedra. K2TbGe2O7 is a terbium(4+) pyrogermanate that is isostructural with K2ZrGe2O7 and displays a rare stable Tb4+ oxidation state in the solid state.",

author = "Kyle Fulle and Sanjeewa, \{Liurukara D.\} and McMillen, \{Colin D.\} and Yimei Wen and Rajamanthrilage, \{Apeksha C.\} and Anker, \{Jeffrey N.\} and George Chumanov and Kolis, \{Joseph W.\}",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = jun,

day = "5",

doi = "10.1021/acs.inorgchem.7b00821",

language = "English",

volume = "56",

pages = "6044--6047",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - One-Pot Hydrothermal Synthesis of TbIII13(GeO4)6O7(OH) and K2TbIVGe2O7

T2 - Preparation of a Stable Terbium(4+) Complex

AU - Fulle, Kyle

AU - Sanjeewa, Liurukara D.

AU - McMillen, Colin D.

AU - Wen, Yimei

AU - Rajamanthrilage, Apeksha C.

AU - Anker, Jeffrey N.

AU - Chumanov, George

AU - Kolis, Joseph W.

PY - 2017/6/5

Y1 - 2017/6/5

N2 - Two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R3̅, is built up of isolated GeO4 units, and contains a complex arrangement of terbium oxide polyhedra. K2TbGe2O7 is a terbium(4+) pyrogermanate that is isostructural with K2ZrGe2O7 and displays a rare stable Tb4+ oxidation state in the solid state.

AB - Two terbium germanates have been synthesized via high-temperature and high-pressure hydrothermal synthesis with 20 M KOH as a mineralizer using Tb4O7 as a starting material. Tb13(GeO4)6O7(OH) crystallizes in trigonal space group R3̅, is built up of isolated GeO4 units, and contains a complex arrangement of terbium oxide polyhedra. K2TbGe2O7 is a terbium(4+) pyrogermanate that is isostructural with K2ZrGe2O7 and displays a rare stable Tb4+ oxidation state in the solid state.

UR - https://www.scopus.com/pages/publications/85020268272

U2 - 10.1021/acs.inorgchem.7b00821

DO - 10.1021/acs.inorgchem.7b00821

M3 - Article

C2 - 28537716

AN - SCOPUS:85020268272

SN - 0020-1669

VL - 56

SP - 6044

EP - 6047

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

One-Pot Hydrothermal Synthesis of Tb^III₁₃(GeO₄)₆O₇(OH) and K₂Tb^IVGe₂O₇: Preparation of a Stable Terbium(4+) Complex

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