On the loss of protective scale formation in creep-resistant, alumina-forming austenitic stainless steels at 900°C in air

M. P. Brady, Y. Yamamoto, B. A. Pint, M. L. Santella, P. J. Maziasz, L. R. Walker

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

37 Scopus citations

Abstract

A family of creep-resistant, Al2O3-forming austenitic (AFA) stainless steels was recently developed. The alloys exhibit excellent oxidation resistance up to ∼800°C, but are susceptible to internal attack of Al at higher temperatures. In the present work, higher levels of Ni, Cr, Al, and Nb additions were found to correlate with improved oxidation behavior at 900°C in air. The alloys generally appeared to be initially capable of external Al2O3 scale formation, with a subsequent transition to internal attack of Al (internal oxidation and internal nitridation) that is dependent on alloy composition. Compositional profiles at the alloy/scale interface suggest that the transition to internal oxidation is preceded by subsurface depletion of Al in the lower-Al compositions. In higher Al-containing compositions, NiAl second-phase precipitates act as an Al reservoir, and Al depletion may not be a key factor. Alloy design directions to increase the upper-temperature limit of protective Al2O3 scale formation in these alloys are discussed.

Original languageEnglish
Title of host publicationHigh Temperature Corrosion and Protection of Materials 7 - Selected, peer Reviewed Papers from 7th International Symposium on High Temperature Corrosion and Protection of Materials
EditorsPierre Steinmetz, Stephane Mathieu, Ian G. Wright, Alain Galerie, Alain Galerie, Daniel Monceau
PublisherTrans Tech Publications Ltd
Pages725-732
Number of pages8
ISBN (Electronic)9780878493609
DOIs
StatePublished - 2008
Event7th International Symposium on High Temperature Corrosion and Protection of Materials - Les Embiez, France
Duration: May 18 2008May 23 2008

Publication series

NameMaterials Science Forum
Volume595-598 PART 2
ISSN (Print)0255-5476
ISSN (Electronic)1662-9752

Conference

Conference7th International Symposium on High Temperature Corrosion and Protection of Materials
Country/TerritoryFrance
CityLes Embiez
Period05/18/0805/23/08

Keywords

  • Alumina
  • Austenitic stainless steel
  • Internal oxidation
  • Third-element effect

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