Oligomeric phosphate clusters in macrocyclic channels

Subhamay Pramanik; Pall Thordarson; Victor W. Day; Kristin Bowman-James

doi:10.1039/d2ce00756h

Oligomeric phosphate clusters in macrocyclic channels

Subhamay Pramanik
, Pall Thordarson
, Victor W. Day
, Kristin Bowman-James

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A 36-membered macrocycle, H₃1³⁺, crystallizes with a mixture of five phosphates with valences HPO₄²⁻, H₂PO₄⁻, and H₃PO₄. The macrocycles form sandwich-like channels for clusters of six phosphates interconnected through oligomeric chains of water-linked phosphates and phosphoric acid molecules. Binding studies indicate 3 : 1 phosphate : macrocycle associations in keeping with 6 : 2 phosphate : macrocycle “sandwiches.”

Original language	English
Pages (from-to)	8047-8051
Number of pages	5
Journal	CrystEngComm
Volume	24
Issue number	46
DOIs	https://doi.org/10.1039/d2ce00756h
State	Published - Sep 14 2022
Externally published	Yes

Funding

The authors thank the National Science Foundation (CHE-1710535) for support of this work and (CHE-0923449) for the purchase of the X-ray diffractometer. The authors would also like to thank Dr. Nigam Rath for discussions concerning the crystal structure.

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10.1039/d2ce00756h

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title = "Oligomeric phosphate clusters in macrocyclic channels",

abstract = "A 36-membered macrocycle, H313+, crystallizes with a mixture of five phosphates with valences HPO42−, H2PO4−, and H3PO4. The macrocycles form sandwich-like channels for clusters of six phosphates interconnected through oligomeric chains of water-linked phosphates and phosphoric acid molecules. Binding studies indicate 3 : 1 phosphate : macrocycle associations in keeping with 6 : 2 phosphate : macrocycle “sandwiches.”",

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AU - Thordarson, Pall

AU - Day, Victor W.

AU - Bowman-James, Kristin

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Y1 - 2022/9/14

N2 - A 36-membered macrocycle, H313+, crystallizes with a mixture of five phosphates with valences HPO42−, H2PO4−, and H3PO4. The macrocycles form sandwich-like channels for clusters of six phosphates interconnected through oligomeric chains of water-linked phosphates and phosphoric acid molecules. Binding studies indicate 3 : 1 phosphate : macrocycle associations in keeping with 6 : 2 phosphate : macrocycle “sandwiches.”

AB - A 36-membered macrocycle, H313+, crystallizes with a mixture of five phosphates with valences HPO42−, H2PO4−, and H3PO4. The macrocycles form sandwich-like channels for clusters of six phosphates interconnected through oligomeric chains of water-linked phosphates and phosphoric acid molecules. Binding studies indicate 3 : 1 phosphate : macrocycle associations in keeping with 6 : 2 phosphate : macrocycle “sandwiches.”

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DO - 10.1039/d2ce00756h

M3 - Article

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ER -

Oligomeric phosphate clusters in macrocyclic channels

Abstract

Funding

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