Observation of a volatile astatine hydroxide species in online gas-adsorption thermochromatography experiments

Nadine Mariel Chiera; Nikolay Viktorovich Aksenov; Yuri Valerianovich Albin; Aleksandr Yurievich Bodrov; Gospodin Apostolov Bozhikov; Ilya Chuprakov; Sergei Nikolaevich Dmitriev; Rugard Dressler; Robert Eichler; Benjamin Kraus; Alexander Shavkatovich Madumarov; David Piguet; Alexei Valentinovich Sabelnikov; Alexander Vögele; Yves Wittwer; Patrick Steinegger

doi:10.1080/00268976.2023.2272685

Observation of a volatile astatine hydroxide species in online gas-adsorption thermochromatography experiments

Nadine Mariel Chiera, Nikolay Viktorovich Aksenov, Yuri Valerianovich Albin, Aleksandr Yurievich Bodrov, Gospodin Apostolov Bozhikov, Ilya Chuprakov, Sergei Nikolaevich Dmitriev, Rugard Dressler, Robert Eichler, Benjamin Kraus, Alexander Shavkatovich Madumarov, David Piguet, Alexei Valentinovich Sabelnikov, Alexander Vögele, Yves Wittwer, Patrick Steinegger

Medical Isotopes and Development

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

During recent online gas-phase experiments with the transactinide elements copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114), the transport of a volatile astatine species was observed. Comprehensive Monte Carlo simulations of the deposition pattern of ²¹¹At on the given quartz, selenium, and gold chromatographic surfaces were carried out, and the corresponding adsorption enthalpies were estimated. Based on the astatine speciation from previous model experiments, the compound observed in this work was ascribed to AtOH/HAtO. The herein presented results assist in paving the way toward a future chemical characterization of tennessine (Ts, Z = 117) with similar gas adsorption chromatography techniques.

Original language	English
Article number	e2272685
Journal	Molecular Physics
DOIs	https://doi.org/10.1080/00268976.2023.2272685
State	Accepted/In press - 2023

Funding

The authors would like to thank the U400 accelerator staff of FLNR for the provision of the Ca ion beam. This work was supported by the Swiss National Science Foundation under Grant 200021_162769. 48 Notice: This manuscript has been authored by UT-Battelle, LLC, under contract DE-AC05-00OR22725 with the US Department of Energy (DOE). The US government retains and the publisher, by accepting the article for publication, acknowledges that the US government retains a nonexclusive, paid-up, irrevocable, worldwide license to publish or reproduce the published form of this manuscript, or allow others to do so, for US government purposes. DOE will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan ( https://www.energy.gov/doe-public-access-plan ).

Keywords

Astatine
adsorption
gas-chromatography
tennessine
transactinides

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10.1080/00268976.2023.2272685

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Chiera, N. M., Aksenov, N. V., Albin, Y. V., Bodrov, A. Y., Bozhikov, G. A., Chuprakov, I., Dmitriev, S. N., Dressler, R., Eichler, R., Kraus, B., Madumarov, A. S., Piguet, D., Sabelnikov, A. V., Vögele, A., Wittwer, Y., & Steinegger, P. (Accepted/In press). Observation of a volatile astatine hydroxide species in online gas-adsorption thermochromatography experiments. Molecular Physics, Article e2272685. https://doi.org/10.1080/00268976.2023.2272685

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title = "Observation of a volatile astatine hydroxide species in online gas-adsorption thermochromatography experiments",

abstract = "During recent online gas-phase experiments with the transactinide elements copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114), the transport of a volatile astatine species was observed. Comprehensive Monte Carlo simulations of the deposition pattern of 211At on the given quartz, selenium, and gold chromatographic surfaces were carried out, and the corresponding adsorption enthalpies were estimated. Based on the astatine speciation from previous model experiments, the compound observed in this work was ascribed to AtOH/HAtO. The herein presented results assist in paving the way toward a future chemical characterization of tennessine (Ts, Z = 117) with similar gas adsorption chromatography techniques.",

keywords = "Astatine, adsorption, gas-chromatography, tennessine, transactinides",

author = "Chiera, {Nadine Mariel} and Aksenov, {Nikolay Viktorovich} and Albin, {Yuri Valerianovich} and Bodrov, {Aleksandr Yurievich} and Bozhikov, {Gospodin Apostolov} and Ilya Chuprakov and Dmitriev, {Sergei Nikolaevich} and Rugard Dressler and Robert Eichler and Benjamin Kraus and Madumarov, {Alexander Shavkatovich} and David Piguet and Sabelnikov, {Alexei Valentinovich} and Alexander V{\"o}gele and Yves Wittwer and Patrick Steinegger",

note = "Publisher Copyright: {\textcopyright} 2023 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group.",

year = "2023",

doi = "10.1080/00268976.2023.2272685",

language = "English",

journal = "Molecular Physics",

issn = "0026-8976",

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Chiera, NM, Aksenov, NV, Albin, YV, Bodrov, AY, Bozhikov, GA, Chuprakov, I, Dmitriev, SN, Dressler, R, Eichler, R, Kraus, B, Madumarov, AS, Piguet, D, Sabelnikov, AV, Vögele, A, Wittwer, Y & Steinegger, P 2023, 'Observation of a volatile astatine hydroxide species in online gas-adsorption thermochromatography experiments', Molecular Physics. https://doi.org/10.1080/00268976.2023.2272685

TY - JOUR

T1 - Observation of a volatile astatine hydroxide species in online gas-adsorption thermochromatography experiments

AU - Chiera, Nadine Mariel

AU - Aksenov, Nikolay Viktorovich

AU - Albin, Yuri Valerianovich

AU - Bodrov, Aleksandr Yurievich

AU - Bozhikov, Gospodin Apostolov

AU - Chuprakov, Ilya

AU - Dmitriev, Sergei Nikolaevich

AU - Dressler, Rugard

AU - Eichler, Robert

AU - Kraus, Benjamin

AU - Madumarov, Alexander Shavkatovich

AU - Piguet, David

AU - Sabelnikov, Alexei Valentinovich

AU - Vögele, Alexander

AU - Wittwer, Yves

AU - Steinegger, Patrick

PY - 2023

Y1 - 2023

N2 - During recent online gas-phase experiments with the transactinide elements copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114), the transport of a volatile astatine species was observed. Comprehensive Monte Carlo simulations of the deposition pattern of 211At on the given quartz, selenium, and gold chromatographic surfaces were carried out, and the corresponding adsorption enthalpies were estimated. Based on the astatine speciation from previous model experiments, the compound observed in this work was ascribed to AtOH/HAtO. The herein presented results assist in paving the way toward a future chemical characterization of tennessine (Ts, Z = 117) with similar gas adsorption chromatography techniques.

AB - During recent online gas-phase experiments with the transactinide elements copernicium (Cn, Z = 112) and flerovium (Fl, Z = 114), the transport of a volatile astatine species was observed. Comprehensive Monte Carlo simulations of the deposition pattern of 211At on the given quartz, selenium, and gold chromatographic surfaces were carried out, and the corresponding adsorption enthalpies were estimated. Based on the astatine speciation from previous model experiments, the compound observed in this work was ascribed to AtOH/HAtO. The herein presented results assist in paving the way toward a future chemical characterization of tennessine (Ts, Z = 117) with similar gas adsorption chromatography techniques.

KW - Astatine

KW - adsorption

KW - gas-chromatography

KW - tennessine

KW - transactinides

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U2 - 10.1080/00268976.2023.2272685

DO - 10.1080/00268976.2023.2272685

M3 - Article

AN - SCOPUS:85175535150

SN - 0026-8976

JO - Molecular Physics

JF - Molecular Physics

M1 - e2272685

ER -

Observation of a volatile astatine hydroxide species in online gas-adsorption thermochromatography experiments

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