Nuclear magnetic resonance and dielectric spectroscopy of a simple supercooled liquid: 2-methyl tetrahydrofuran

F. Qi; T. El Goresy; R. Böhmer; A. Döß; G. Diezemann; G. Hinze; H. Sillescu; T. Blochowicz; C. Gainaru; E. Rössler; H. Zimmermann

doi:10.1063/1.1563599

Nuclear magnetic resonance and dielectric spectroscopy of a simple supercooled liquid: 2-methyl tetrahydrofuran

F. Qi, T. El Goresy, R. Böhmer, A. Döß, G. Diezemann, G. Hinze, H. Sillescu, T. Blochowicz, C. Gainaru, E. Rössler, H. Zimmermann

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

The present dielectric and nuclear magnetic resonance (NMR) experiments show that viscous 2-methyl tetrahydrofuran (MTHF) exhibits a number of features typical for glass-forming liquids. These include the existence of a high-frequency contribution to the dielectric loss as well as indications for a secondary process which bears the signature of a Johari-Goldstein relaxation. The dielectric losses of MTHF were analyzed using an expression based on a generalized gamma function and yielded parameters that were similar to those of another small-molecule viscous liquid, meta-fluoroaniline.

Original language	English
Pages (from-to)	7431-7438
Number of pages	8
Journal	Journal of Chemical Physics
Volume	118
Issue number	16
DOIs	https://doi.org/10.1063/1.1563599
State	Published - Apr 22 2003
Externally published	Yes

Access to Document

10.1063/1.1563599

Cite this

@article{f302b377a45146f198eaf13070511285,

title = "Nuclear magnetic resonance and dielectric spectroscopy of a simple supercooled liquid: 2-methyl tetrahydrofuran",

abstract = "The present dielectric and nuclear magnetic resonance (NMR) experiments show that viscous 2-methyl tetrahydrofuran (MTHF) exhibits a number of features typical for glass-forming liquids. These include the existence of a high-frequency contribution to the dielectric loss as well as indications for a secondary process which bears the signature of a Johari-Goldstein relaxation. The dielectric losses of MTHF were analyzed using an expression based on a generalized gamma function and yielded parameters that were similar to those of another small-molecule viscous liquid, meta-fluoroaniline.",

author = "F. Qi and {El Goresy}, T. and R. B{\"o}hmer and A. D{\"o}{\ss} and G. Diezemann and G. Hinze and H. Sillescu and T. Blochowicz and C. Gainaru and E. R{\"o}ssler and H. Zimmermann",

year = "2003",

month = apr,

day = "22",

doi = "10.1063/1.1563599",

language = "English",

volume = "118",

pages = "7431--7438",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "16",

}

TY - JOUR

T1 - Nuclear magnetic resonance and dielectric spectroscopy of a simple supercooled liquid

T2 - 2-methyl tetrahydrofuran

AU - Qi, F.

AU - El Goresy, T.

AU - Böhmer, R.

AU - Döß, A.

AU - Diezemann, G.

AU - Hinze, G.

AU - Sillescu, H.

AU - Blochowicz, T.

AU - Gainaru, C.

AU - Rössler, E.

AU - Zimmermann, H.

PY - 2003/4/22

Y1 - 2003/4/22

N2 - The present dielectric and nuclear magnetic resonance (NMR) experiments show that viscous 2-methyl tetrahydrofuran (MTHF) exhibits a number of features typical for glass-forming liquids. These include the existence of a high-frequency contribution to the dielectric loss as well as indications for a secondary process which bears the signature of a Johari-Goldstein relaxation. The dielectric losses of MTHF were analyzed using an expression based on a generalized gamma function and yielded parameters that were similar to those of another small-molecule viscous liquid, meta-fluoroaniline.

AB - The present dielectric and nuclear magnetic resonance (NMR) experiments show that viscous 2-methyl tetrahydrofuran (MTHF) exhibits a number of features typical for glass-forming liquids. These include the existence of a high-frequency contribution to the dielectric loss as well as indications for a secondary process which bears the signature of a Johari-Goldstein relaxation. The dielectric losses of MTHF were analyzed using an expression based on a generalized gamma function and yielded parameters that were similar to those of another small-molecule viscous liquid, meta-fluoroaniline.

UR - http://www.scopus.com/inward/record.url?scp=0037724988&partnerID=8YFLogxK

U2 - 10.1063/1.1563599

DO - 10.1063/1.1563599

M3 - Article

AN - SCOPUS:0037724988

SN - 0021-9606

VL - 118

SP - 7431

EP - 7438

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 16

ER -

Nuclear magnetic resonance and dielectric spectroscopy of a simple supercooled liquid: 2-methyl tetrahydrofuran

Abstract

Access to Document

Other files and links

Fingerprint

Cite this