Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

Assunta Marrocchi; Peter Adriaensens; Elena Bartollini; Balaka Barkakati; Robert Carleer; Jihua Chen; Dale K. Hensley; Chiara Petrucci; Marco Tassi; Luigi Vaccaro

doi:10.1016/j.eurpolymj.2015.10.002

Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

Assunta Marrocchi, Peter Adriaensens, Elena Bartollini, Balaka Barkakati, Robert Carleer, Jihua Chen, Dale K. Hensley, Chiara Petrucci, Marco Tassi, Luigi Vaccaro

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis(4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.

Original language	English
Pages (from-to)	391-401
Number of pages	11
Journal	European Polymer Journal
Volume	73
DOIs	https://doi.org/10.1016/j.eurpolymj.2015.10.002
State	Published - Dec 1 2015

Funding

This research has been developed and partially financed within the National project “BIT3G“ – Italian Green Chemistry Cluster .

Keywords

Gel-type resins
Green chemistry
Heterogeneous catalyst
Polymer supports
Polystyrenes

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10.1016/j.eurpolymj.2015.10.002

Cite this

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title = "Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media",

abstract = "A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis(4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.",

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author = "Assunta Marrocchi and Peter Adriaensens and Elena Bartollini and Balaka Barkakati and Robert Carleer and Jihua Chen and Hensley, {Dale K.} and Chiara Petrucci and Marco Tassi and Luigi Vaccaro",

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doi = "10.1016/j.eurpolymj.2015.10.002",

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T1 - Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

AU - Marrocchi, Assunta

AU - Adriaensens, Peter

AU - Bartollini, Elena

AU - Barkakati, Balaka

AU - Carleer, Robert

AU - Chen, Jihua

AU - Hensley, Dale K.

AU - Petrucci, Chiara

AU - Tassi, Marco

AU - Vaccaro, Luigi

PY - 2015/12/1

Y1 - 2015/12/1

N2 - A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis(4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.

AB - A novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis(4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.

KW - Gel-type resins

KW - Green chemistry

KW - Heterogeneous catalyst

KW - Polymer supports

KW - Polystyrenes

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DO - 10.1016/j.eurpolymj.2015.10.002

M3 - Article

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VL - 73

SP - 391

EP - 401

JO - European Polymer Journal

JF - European Polymer Journal

ER -

Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

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