New tricks for old molecules: Development and application of porous N-doped, carbonaceous membranes for CO2 separation

Xiang Zhu; Chengcheng Tian; Songhai Chai; Kimberly Nelson; Kee Sung Han; Edward W. Hagaman; Gabriel M. Veith; Shannon M. Mahurin; Honglai Liu; Sheng Dai

doi:10.1002/adma.201300793

New tricks for old molecules: Development and application of porous N-doped, carbonaceous membranes for CO₂ separation

Xiang Zhu, Chengcheng Tian, Songhai Chai, Kimberly Nelson, Kee Sung Han, Edward W. Hagaman, Gabriel M. Veith, Shannon M. Mahurin, Honglai Liu, Sheng Dai

Research output: Contribution to journal › Article › peer-review

71 Scopus citations

Abstract

A new strategy is successfully applied to "old" acetyl compounds. A free-standing, porous, N-doped carbonaceous membrane is facilely prepared from the thermal treatment of a pyrrole-ring-containing polymeric membrane based on the superacid-catalyzed copolymerization of acetyl monomers. An exceptional ideal CO₂/N₂ permselectivity of 43.2 is achieved with a good CO₂ permeability of 1149.3 Barrer, exceeding the recent upper bound for CO₂/N₂.

Original language	English
Pages (from-to)	4152-4158
Number of pages	7
Journal	Advanced Materials
Volume	25
Issue number	30
DOIs	https://doi.org/10.1002/adma.201300793
State	Published - Aug 14 2013

Keywords

CO separation
N-doped membrane
trimerization of acetyl groups

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10.1002/adma.201300793

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abstract = "A new strategy is successfully applied to {"}old{"} acetyl compounds. A free-standing, porous, N-doped carbonaceous membrane is facilely prepared from the thermal treatment of a pyrrole-ring-containing polymeric membrane based on the superacid-catalyzed copolymerization of acetyl monomers. An exceptional ideal CO2/N2 permselectivity of 43.2 is achieved with a good CO2 permeability of 1149.3 Barrer, exceeding the recent upper bound for CO2/N2.",

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author = "Xiang Zhu and Chengcheng Tian and Songhai Chai and Kimberly Nelson and Han, \{Kee Sung\} and Hagaman, \{Edward W.\} and Veith, \{Gabriel M.\} and Mahurin, \{Shannon M.\} and Honglai Liu and Sheng Dai",

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T2 - Development and application of porous N-doped, carbonaceous membranes for CO2 separation

AU - Zhu, Xiang

AU - Tian, Chengcheng

AU - Chai, Songhai

AU - Nelson, Kimberly

AU - Han, Kee Sung

AU - Hagaman, Edward W.

AU - Veith, Gabriel M.

AU - Mahurin, Shannon M.

AU - Liu, Honglai

AU - Dai, Sheng

PY - 2013/8/14

Y1 - 2013/8/14

N2 - A new strategy is successfully applied to "old" acetyl compounds. A free-standing, porous, N-doped carbonaceous membrane is facilely prepared from the thermal treatment of a pyrrole-ring-containing polymeric membrane based on the superacid-catalyzed copolymerization of acetyl monomers. An exceptional ideal CO2/N2 permselectivity of 43.2 is achieved with a good CO2 permeability of 1149.3 Barrer, exceeding the recent upper bound for CO2/N2.

AB - A new strategy is successfully applied to "old" acetyl compounds. A free-standing, porous, N-doped carbonaceous membrane is facilely prepared from the thermal treatment of a pyrrole-ring-containing polymeric membrane based on the superacid-catalyzed copolymerization of acetyl monomers. An exceptional ideal CO2/N2 permselectivity of 43.2 is achieved with a good CO2 permeability of 1149.3 Barrer, exceeding the recent upper bound for CO2/N2.

KW - CO separation

KW - N-doped membrane

KW - trimerization of acetyl groups

UR - https://www.scopus.com/pages/publications/84882450702

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DO - 10.1002/adma.201300793

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EP - 4158

JO - Advanced Materials

JF - Advanced Materials

IS - 30

ER -

New tricks for old molecules: Development and application of porous N-doped, carbonaceous membranes for CO₂ separation

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Keywords

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