New palladium(II) complexes of (N,N-dimethylamino)alkoxy- 1,3,2-oxazaphospholidine ligands

A. V. Korostylev; O. G. Bondarev; S. Y. Lyubimov; A. Yu Kovalevsky; P. V. Petrovskii; V. A. Davankov; K. N. Gavrilov

doi:10.1016/S0020-1693(99)00473-9

New palladium(II) complexes of (N,N-dimethylamino)alkoxy- 1,3,2-oxazaphospholidine ligands

A. V. Korostylev, O. G. Bondarev, S. Y. Lyubimov, A. Yu Kovalevsky, P. V. Petrovskii, V. A. Davankov, K. N. Gavrilov

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

New P,N-bidentate aminophosphite ligands OCH₂CH₂N(R)PO(CH₂)(n)NMe₂ (2a R = Me, n = 2; 2b R = t-Bu, n = 2; 3 R = t-Bu, n = 3) have been obtained and characterized. Complexation of all the ligands with [PdCl₂(COD)] (COD = 1,5-cyclooctadiene) has been investigated. Ligands 2a,b have been found to form mononuclear chelate complexes [PdCl₂(PN)]. Ligand 3 forms a binuclear compound [PdCl₂(PN)]₂, in which molecules 3 act as P,N-bidentate bridges. The obtained compounds have been characterized by multinuclear NMR, IR spectroscopy, mass spectrometry and sedimentation analysis. The molecular structure of [PdCl₂L] (L = 2b) has been determined by single crystal X-ray diffraction. (C) 2000 Elsevier Science S.A.

Original language	English
Pages (from-to)	1-6
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	303
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(99)00473-9
State	Published - May 15 2000
Externally published	Yes

Funding

This work was supported by the Scientific Training Center of Chemistry of Organometallic Compounds (grant 234, the Federal Target Program ‘Integration’) and by the Scientific Training Center of Biochemistry (project K0559, the Federal Target Program ‘Integration’).

Funders	Funder number
Federal Target Program
Scientific Training Center of Biochemistry	K0559

Keywords

Aminophosphite complexes
Crystal structures
P,N-ligand complexes
Palladium complexes

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10.1016/S0020-1693(99)00473-9

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title = "New palladium(II) complexes of (N,N-dimethylamino)alkoxy- 1,3,2-oxazaphospholidine ligands",

abstract = "New P,N-bidentate aminophosphite ligands OCH2CH2N(R)PO(CH2)(n)NMe2 (2a R = Me, n = 2; 2b R = t-Bu, n = 2; 3 R = t-Bu, n = 3) have been obtained and characterized. Complexation of all the ligands with [PdCl2(COD)] (COD = 1,5-cyclooctadiene) has been investigated. Ligands 2a,b have been found to form mononuclear chelate complexes [PdCl2(PN)]. Ligand 3 forms a binuclear compound [PdCl2(PN)]2, in which molecules 3 act as P,N-bidentate bridges. The obtained compounds have been characterized by multinuclear NMR, IR spectroscopy, mass spectrometry and sedimentation analysis. The molecular structure of [PdCl2L] (L = 2b) has been determined by single crystal X-ray diffraction. (C) 2000 Elsevier Science S.A.",

keywords = "Aminophosphite complexes, Crystal structures, P,N-ligand complexes, Palladium complexes",

author = "Korostylev, {A. V.} and Bondarev, {O. G.} and Lyubimov, {S. Y.} and Kovalevsky, {A. Yu} and Petrovskii, {P. V.} and Davankov, {V. A.} and Gavrilov, {K. N.}",

year = "2000",

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doi = "10.1016/S0020-1693(99)00473-9",

language = "English",

volume = "303",

pages = "1--6",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - New palladium(II) complexes of (N,N-dimethylamino)alkoxy- 1,3,2-oxazaphospholidine ligands

AU - Korostylev, A. V.

AU - Bondarev, O. G.

AU - Lyubimov, S. Y.

AU - Kovalevsky, A. Yu

AU - Petrovskii, P. V.

AU - Davankov, V. A.

AU - Gavrilov, K. N.

PY - 2000/5/15

Y1 - 2000/5/15

N2 - New P,N-bidentate aminophosphite ligands OCH2CH2N(R)PO(CH2)(n)NMe2 (2a R = Me, n = 2; 2b R = t-Bu, n = 2; 3 R = t-Bu, n = 3) have been obtained and characterized. Complexation of all the ligands with [PdCl2(COD)] (COD = 1,5-cyclooctadiene) has been investigated. Ligands 2a,b have been found to form mononuclear chelate complexes [PdCl2(PN)]. Ligand 3 forms a binuclear compound [PdCl2(PN)]2, in which molecules 3 act as P,N-bidentate bridges. The obtained compounds have been characterized by multinuclear NMR, IR spectroscopy, mass spectrometry and sedimentation analysis. The molecular structure of [PdCl2L] (L = 2b) has been determined by single crystal X-ray diffraction. (C) 2000 Elsevier Science S.A.

AB - New P,N-bidentate aminophosphite ligands OCH2CH2N(R)PO(CH2)(n)NMe2 (2a R = Me, n = 2; 2b R = t-Bu, n = 2; 3 R = t-Bu, n = 3) have been obtained and characterized. Complexation of all the ligands with [PdCl2(COD)] (COD = 1,5-cyclooctadiene) has been investigated. Ligands 2a,b have been found to form mononuclear chelate complexes [PdCl2(PN)]. Ligand 3 forms a binuclear compound [PdCl2(PN)]2, in which molecules 3 act as P,N-bidentate bridges. The obtained compounds have been characterized by multinuclear NMR, IR spectroscopy, mass spectrometry and sedimentation analysis. The molecular structure of [PdCl2L] (L = 2b) has been determined by single crystal X-ray diffraction. (C) 2000 Elsevier Science S.A.

KW - Aminophosphite complexes

KW - Crystal structures

KW - P,N-ligand complexes

KW - Palladium complexes

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DO - 10.1016/S0020-1693(99)00473-9

M3 - Article

AN - SCOPUS:0034656804

SN - 0020-1693

VL - 303

SP - 1

EP - 6

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

New palladium(II) complexes of (N,N-dimethylamino)alkoxy- 1,3,2-oxazaphospholidine ligands

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