Abstract
New molecular complex of C60 with covalently linked (FeIIITPP)2O · C60 dimer has been obtained. The complex has isolated packing of fullerenes in which fullerene molecule is embraced in a pocket built by porphyrins. (FeIIITPP)2O preserves its initial geometry in the complex. The Fe···C(C60) contacts are in the 3.239-3.513 A range indicating the absence of Fe-C60 coordination. This results in the similarity of the EPR spectra of the complex and parent (FeIIITPP)2O.
Original language | English |
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Pages (from-to) | 215-219 |
Number of pages | 5 |
Journal | Fullerenes Nanotubes and Carbon Nanostructures |
Volume | 12 |
Issue number | 1-2 |
DOIs | |
State | Published - Jan 2 2005 |
Externally published | Yes |
Funding
The work was supported by the Russian Program “Fullerenes and Atomic Clusters” and the RFFR grant N 03-03-32699a.
Keywords
- (FeTPP)O
- Crystal structure
- EPR spectra
- Fullerene C
- Porphyrin