New hybrid diphosphates Ln2(NH2(CH2) 2NH2)(HP2O7)2·4 H2O (Ln=Eu, Tb, Er): Synthesis, single crystal and powder X-ray crystal structure

Francesco Capitelli; Brahim El Bali; Rachid Essehli; Mohammed Lachkar; Iván Da Silva

doi:10.1524/zkri.2006.221.12.788

New hybrid diphosphates Ln₂(NH₂(CH₂) ₂NH₂)(HP₂O₇)₂·4 H₂O (Ln=Eu, Tb, Er): Synthesis, single crystal and powder X-ray crystal structure

Francesco Capitelli
, Brahim El Bali
, Rachid Essehli
, Mohammed Lachkar
, Iván Da Silva

Emerging and Solid-State Batteries

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

Crystals of lanthanide ethylenediamine diphosphates Ln₂(NH ₂(CH₂)₂NH₂)(HP₂O ₇)₂·4 H₂O (Ln = Eu (1), Tb (2), Er (2)) have been synthesized and investigated by single crystal X-ray diffractometry (Eu and Tb phases) and by powder X-ray diffractometry (Er phase). The three structures resulted to be isostructural within triclinic space group P1, with unit cell parameters of a = 6.5050(6) Å; b = 6.9990(2) Å; c = 9.8450(9) Å; α = 81.548(5)°; β = 80.631(19)°; γ = 88.369(9)°; V = 437.44(6) Å³ (1), a = 6.4360(7) Å; b = 6.9480(12) Å; c = 9.816(4) Å; α = 81.987(19)°; β = 80.595(16)°; γ = 88.591(13)°; V = 428.82(19) Å³ (2), a = 6.39658(2) Å; b = 6.86682(2) Å; c = 9.78849(3) Å; α = 81.6811(4)°; β = 80.2304(3)°; γ = 88.3812(3)°; V = 419.255(3) Å³ (3). The three-dimensional network is built up by the repetition of ab-parallel layers of LnO₈ polyhedra corner-sharing with (HP₂O₇) groups; ethylenediamine molecules lie between such layers, acting both as receptors and donors in strong hydrogen bonds which assure the stabilizing of the entire framework.

Original language	English
Pages (from-to)	788-794
Number of pages	7
Journal	Zeitschrift fur Kristallographie
Volume	221
Issue number	12
DOIs	https://doi.org/10.1524/zkri.2006.221.12.788
State	Published - 2006

Keywords

Diphosphate
Ethylenediamine
Hydrogen bond
Lanthanide
Powder diffraction structure analysis
Single crystal structure analysis
X-ray diffraction

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10.1524/zkri.2006.221.12.788

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@article{e239c6e42ba34ffe8a93c7097ab54e91,

title = "New hybrid diphosphates Ln2(NH2(CH2) 2NH2)(HP2O7)2·4 H2O (Ln=Eu, Tb, Er): Synthesis, single crystal and powder X-ray crystal structure",

abstract = "Crystals of lanthanide ethylenediamine diphosphates Ln2(NH 2(CH2)2NH2)(HP2O 7)2·4 H2O (Ln = Eu (1), Tb (2), Er (2)) have been synthesized and investigated by single crystal X-ray diffractometry (Eu and Tb phases) and by powder X-ray diffractometry (Er phase). The three structures resulted to be isostructural within triclinic space group P1, with unit cell parameters of a = 6.5050(6) {\AA}; b = 6.9990(2) {\AA}; c = 9.8450(9) {\AA}; α = 81.548(5)°; β = 80.631(19)°; γ = 88.369(9)°; V = 437.44(6) {\AA}3 (1), a = 6.4360(7) {\AA}; b = 6.9480(12) {\AA}; c = 9.816(4) {\AA}; α = 81.987(19)°; β = 80.595(16)°; γ = 88.591(13)°; V = 428.82(19) {\AA}3 (2), a = 6.39658(2) {\AA}; b = 6.86682(2) {\AA}; c = 9.78849(3) {\AA}; α = 81.6811(4)°; β = 80.2304(3)°; γ = 88.3812(3)°; V = 419.255(3) {\AA}3 (3). The three-dimensional network is built up by the repetition of ab-parallel layers of LnO8 polyhedra corner-sharing with (HP2O7) groups; ethylenediamine molecules lie between such layers, acting both as receptors and donors in strong hydrogen bonds which assure the stabilizing of the entire framework.",

keywords = "Diphosphate, Ethylenediamine, Hydrogen bond, Lanthanide, Powder diffraction structure analysis, Single crystal structure analysis, X-ray diffraction",

author = "Francesco Capitelli and \{El Bali\}, Brahim and Rachid Essehli and Mohammed Lachkar and \{Da Silva\}, Iv{\'a}n",

year = "2006",

doi = "10.1524/zkri.2006.221.12.788",

language = "English",

volume = "221",

pages = "788--794",

journal = "Zeitschrift fur Kristallographie",

issn = "0044-2968",

publisher = "De Gruyter",

number = "12",

}

TY - JOUR

T1 - New hybrid diphosphates Ln2(NH2(CH2) 2NH2)(HP2O7)2·4 H2O (Ln=Eu, Tb, Er)

T2 - Synthesis, single crystal and powder X-ray crystal structure

AU - Capitelli, Francesco

AU - El Bali, Brahim

AU - Essehli, Rachid

AU - Lachkar, Mohammed

AU - Da Silva, Iván

PY - 2006

Y1 - 2006

N2 - Crystals of lanthanide ethylenediamine diphosphates Ln2(NH 2(CH2)2NH2)(HP2O 7)2·4 H2O (Ln = Eu (1), Tb (2), Er (2)) have been synthesized and investigated by single crystal X-ray diffractometry (Eu and Tb phases) and by powder X-ray diffractometry (Er phase). The three structures resulted to be isostructural within triclinic space group P1, with unit cell parameters of a = 6.5050(6) Å; b = 6.9990(2) Å; c = 9.8450(9) Å; α = 81.548(5)°; β = 80.631(19)°; γ = 88.369(9)°; V = 437.44(6) Å3 (1), a = 6.4360(7) Å; b = 6.9480(12) Å; c = 9.816(4) Å; α = 81.987(19)°; β = 80.595(16)°; γ = 88.591(13)°; V = 428.82(19) Å3 (2), a = 6.39658(2) Å; b = 6.86682(2) Å; c = 9.78849(3) Å; α = 81.6811(4)°; β = 80.2304(3)°; γ = 88.3812(3)°; V = 419.255(3) Å3 (3). The three-dimensional network is built up by the repetition of ab-parallel layers of LnO8 polyhedra corner-sharing with (HP2O7) groups; ethylenediamine molecules lie between such layers, acting both as receptors and donors in strong hydrogen bonds which assure the stabilizing of the entire framework.

AB - Crystals of lanthanide ethylenediamine diphosphates Ln2(NH 2(CH2)2NH2)(HP2O 7)2·4 H2O (Ln = Eu (1), Tb (2), Er (2)) have been synthesized and investigated by single crystal X-ray diffractometry (Eu and Tb phases) and by powder X-ray diffractometry (Er phase). The three structures resulted to be isostructural within triclinic space group P1, with unit cell parameters of a = 6.5050(6) Å; b = 6.9990(2) Å; c = 9.8450(9) Å; α = 81.548(5)°; β = 80.631(19)°; γ = 88.369(9)°; V = 437.44(6) Å3 (1), a = 6.4360(7) Å; b = 6.9480(12) Å; c = 9.816(4) Å; α = 81.987(19)°; β = 80.595(16)°; γ = 88.591(13)°; V = 428.82(19) Å3 (2), a = 6.39658(2) Å; b = 6.86682(2) Å; c = 9.78849(3) Å; α = 81.6811(4)°; β = 80.2304(3)°; γ = 88.3812(3)°; V = 419.255(3) Å3 (3). The three-dimensional network is built up by the repetition of ab-parallel layers of LnO8 polyhedra corner-sharing with (HP2O7) groups; ethylenediamine molecules lie between such layers, acting both as receptors and donors in strong hydrogen bonds which assure the stabilizing of the entire framework.

KW - Diphosphate

KW - Ethylenediamine

KW - Hydrogen bond

KW - Lanthanide

KW - Powder diffraction structure analysis

KW - Single crystal structure analysis

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/33845655997

U2 - 10.1524/zkri.2006.221.12.788

DO - 10.1524/zkri.2006.221.12.788

M3 - Article

AN - SCOPUS:33845655997

SN - 0044-2968

VL - 221

SP - 788

EP - 794

JO - Zeitschrift fur Kristallographie

JF - Zeitschrift fur Kristallographie

IS - 12

ER -

New hybrid diphosphates Ln₂(NH₂(CH₂) ₂NH₂)(HP₂O₇)₂·4 H₂O (Ln=Eu, Tb, Er): Synthesis, single crystal and powder X-ray crystal structure

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