Neutron spectroscopy of fullerite hydrogenated under high pressures

A. I. Kolesnikov; V. E. Antonov; I. O. Bashkin; J. C. Li; A. P. Moravsky; E. G. Ponyatovsky; J. Tomkinson

doi:10.1016/S0921-4526(98)01403-3

Neutron spectroscopy of fullerite hydrogenated under high pressures

A. I. Kolesnikov, V. E. Antonov, I. O. Bashkin, J. C. Li, A. P. Moravsky, E. G. Ponyatovsky, J. Tomkinson

Research output: Contribution to journal › Conference article › peer-review

21 Scopus citations

Abstract

A new hydrofullerite was synthesized when the C₆₀ fullerite was treated under a hydrogen gas pressure of 30 kbar at 620 K for 24 h and quenched. The inelastic neutron scattering spectra of the as-prepared sample and that after annealing at 300 K showed that the as-prepared hydrofullerite consisted of C₆₀H_x molecules and interstitially dissolved molecular hydrogen. Both spectra exhibited peaks at 13 meV characteristic of polymeric fullerites.

Original language	English
Pages (from-to)	436-438
Number of pages	3
Journal	Physica B: Physics of Condensed Matter
Volume	263-264
DOIs	https://doi.org/10.1016/S0921-4526(98)01403-3
State	Published - Mar 1999
Externally published	Yes
Event	Proceedings of the 1998 9th International Conference on Phonon Scattering in Condensed Matter, PHONONS 98 - Lancaster, Great Britain Duration: Jul 26 1998 → Jul 31 1998

Funding

We thank the EPSRC for access to the ISIS pulsed neutron source. This work was supported in part by the Russian R&D Programme “Fullerenes and Atomic Clusters” and by the Grants No. 96-02-17522 and 96-15-96808 from the Russian Foundation for Basic Research.

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10.1016/S0921-4526(98)01403-3

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title = "Neutron spectroscopy of fullerite hydrogenated under high pressures",

abstract = "A new hydrofullerite was synthesized when the C60 fullerite was treated under a hydrogen gas pressure of 30 kbar at 620 K for 24 h and quenched. The inelastic neutron scattering spectra of the as-prepared sample and that after annealing at 300 K showed that the as-prepared hydrofullerite consisted of C60Hx molecules and interstitially dissolved molecular hydrogen. Both spectra exhibited peaks at 13 meV characteristic of polymeric fullerites.",

author = "Kolesnikov, \{A. I.\} and Antonov, \{V. E.\} and Bashkin, \{I. O.\} and Li, \{J. C.\} and Moravsky, \{A. P.\} and Ponyatovsky, \{E. G.\} and J. Tomkinson",

year = "1999",

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doi = "10.1016/S0921-4526(98)01403-3",

language = "English",

volume = "263-264",

pages = "436--438",

journal = "Physica B: Physics of Condensed Matter",

issn = "0921-4526",

publisher = "Elsevier",

note = "Proceedings of the 1998 9th International Conference on Phonon Scattering in Condensed Matter, PHONONS 98 ; Conference date: 26-07-1998 Through 31-07-1998",

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TY - JOUR

T1 - Neutron spectroscopy of fullerite hydrogenated under high pressures

AU - Kolesnikov, A. I.

AU - Antonov, V. E.

AU - Bashkin, I. O.

AU - Li, J. C.

AU - Moravsky, A. P.

AU - Ponyatovsky, E. G.

AU - Tomkinson, J.

PY - 1999/3

Y1 - 1999/3

N2 - A new hydrofullerite was synthesized when the C60 fullerite was treated under a hydrogen gas pressure of 30 kbar at 620 K for 24 h and quenched. The inelastic neutron scattering spectra of the as-prepared sample and that after annealing at 300 K showed that the as-prepared hydrofullerite consisted of C60Hx molecules and interstitially dissolved molecular hydrogen. Both spectra exhibited peaks at 13 meV characteristic of polymeric fullerites.

AB - A new hydrofullerite was synthesized when the C60 fullerite was treated under a hydrogen gas pressure of 30 kbar at 620 K for 24 h and quenched. The inelastic neutron scattering spectra of the as-prepared sample and that after annealing at 300 K showed that the as-prepared hydrofullerite consisted of C60Hx molecules and interstitially dissolved molecular hydrogen. Both spectra exhibited peaks at 13 meV characteristic of polymeric fullerites.

UR - https://www.scopus.com/pages/publications/0032636887

U2 - 10.1016/S0921-4526(98)01403-3

DO - 10.1016/S0921-4526(98)01403-3

M3 - Conference article

AN - SCOPUS:0032636887

SN - 0921-4526

VL - 263-264

SP - 436

EP - 438

JO - Physica B: Physics of Condensed Matter

JF - Physica B: Physics of Condensed Matter

T2 - Proceedings of the 1998 9th International Conference on Phonon Scattering in Condensed Matter, PHONONS 98

Y2 - 26 July 1998 through 31 July 1998

ER -

Neutron spectroscopy of fullerite hydrogenated under high pressures

Abstract

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