Neutron reflectivity as a tool to understand polyelectrolyte brushes

S. Michael Kilbey, John F. Ankner

Research output: Contribution to journalReview articlepeer-review

26 Scopus citations

Abstract

Because polyelectrolytes are perhaps the least understood form of soft synthetic matter, polyelectrolyte brushes are important model systems for learning how chain stretching is controlled by conditions that set the charge state of the system, as well as interactions with biological and bio-inspired molecules. Motivated by this fact, we describe situations where the application of neutron reflectivity to the study of polyelectrolyte brushes is poised to deepen understanding of the complex connections between charge and nanostructure. This theme is especially pertinent because the nanoscale structure dictates interactions across interfaces.

Original languageEnglish
Pages (from-to)83-89
Number of pages7
JournalCurrent Opinion in Colloid and Interface Science
Volume17
Issue number2
DOIs
StatePublished - Apr 2012
Externally publishedYes

Funding

S.M. Kilbey acknowledges partial support from the National Science Foundation under Grant No. 0840249 , as well as interactions enabled through the User Programs of the Center for Nanophase Materials Sciences and the Spallation Neutron Source, both of which are sponsored at Oak Ridge National Laboratory by the Office of Science, Department of Energy , under contract No. DE-AC05-00OR22725 .

FundersFunder number
Center for Nanophase Materials Sciences
National Science Foundation0840249
U.S. Department of Energy
Office of Science
Oak Ridge National Laboratory

    Keywords

    • Neutron reflectivity
    • Polyelectrolyte brushes
    • Polyelectrolytes
    • Scattering
    • Structure

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