Neutron Compton scattering as a molecular characterization technique: A study on NaH F2

D. Colognesi, A. Pietropaolo, R. Senesi, A. J. Ramirez-Cuesta

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Abstract

Inelastic neutron scattering experiments were performed at intermediate and high momentum transfers, up to 85-90 -1, to study the proton momentum distribution in polycrystalline sodium hydrogen fluoride (NaH F2) at low temperature (below 5 K). The H mean kinetic energy was extracted and compared to the results from hydrogen-projected density of phonon states derived from intermediate momentum transfer inelastic neutron scattering and lattice dynamics simulations. A reasonable agreement between the two figures was found. In addition, relevant aspects of high momentum transfer neutron scattering from NaH F2 were explored in detail, ranging from an alternative evaluation of final state effects to the role played by the instrumental resolution and to the possibility to reconstruct the potential felt by a proton from its momentum distribution.

Original languageEnglish
Article number174206
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume76
Issue number17
DOIs
StatePublished - Nov 19 2007
Externally publishedYes

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