Neutron and X-ray Diffuse Scattering of Calcium-Stabilized Zirconia

Th Proffen; R. B. Neder; F. Frey

doi:10.1107/S0108768195007920

Neutron and X-ray Diffuse Scattering of Calcium-Stabilized Zirconia

Th Proffen, R. B. Neder, F. Frey

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The defect structure of calcium-stabilized zirconia (CSZ) is described in terms of a correlated distribution of microdomains within the cubic matrix of CSZ. The defect structure consists of two types of defects: microdomains based on a single oxygen vacancy with relaxed neighbouring ions and microdomains based on a pair of oxygen vacancies separated by 3^1/2/2α along <111>. The combined evaluation of neutron and X-ray data shows that the previously published structure of the single vacancy domain has to be modified: All cations next to the oxygen vacancy are most likely zirconium. This modified model leads to good agreement between observed and calculated neutron and X-ray diffraction patterns.

Original language	English
Pages (from-to)	59-65
Number of pages	7
Journal	Acta Crystallographica Section B: Structural Science
Volume	52
Issue number	1
DOIs	https://doi.org/10.1107/S0108768195007920
State	Published - Feb 1 1996
Externally published	Yes

Access to Document

10.1107/S0108768195007920

Cite this

@article{88ee47197da74fb68067e2f556578373,

title = "Neutron and X-ray Diffuse Scattering of Calcium-Stabilized Zirconia",

abstract = "The defect structure of calcium-stabilized zirconia (CSZ) is described in terms of a correlated distribution of microdomains within the cubic matrix of CSZ. The defect structure consists of two types of defects: microdomains based on a single oxygen vacancy with relaxed neighbouring ions and microdomains based on a pair of oxygen vacancies separated by 31/2/2α along <111>. The combined evaluation of neutron and X-ray data shows that the previously published structure of the single vacancy domain has to be modified: All cations next to the oxygen vacancy are most likely zirconium. This modified model leads to good agreement between observed and calculated neutron and X-ray diffraction patterns.",

author = "Th Proffen and Neder, {R. B.} and F. Frey",

year = "1996",

month = feb,

day = "1",

doi = "10.1107/S0108768195007920",

language = "English",

volume = "52",

pages = "59--65",

journal = "Acta Crystallographica Section B: Structural Science",

issn = "0108-7681",

number = "1",

}

TY - JOUR

T1 - Neutron and X-ray Diffuse Scattering of Calcium-Stabilized Zirconia

AU - Proffen, Th

AU - Neder, R. B.

AU - Frey, F.

PY - 1996/2/1

Y1 - 1996/2/1

N2 - The defect structure of calcium-stabilized zirconia (CSZ) is described in terms of a correlated distribution of microdomains within the cubic matrix of CSZ. The defect structure consists of two types of defects: microdomains based on a single oxygen vacancy with relaxed neighbouring ions and microdomains based on a pair of oxygen vacancies separated by 31/2/2α along <111>. The combined evaluation of neutron and X-ray data shows that the previously published structure of the single vacancy domain has to be modified: All cations next to the oxygen vacancy are most likely zirconium. This modified model leads to good agreement between observed and calculated neutron and X-ray diffraction patterns.

AB - The defect structure of calcium-stabilized zirconia (CSZ) is described in terms of a correlated distribution of microdomains within the cubic matrix of CSZ. The defect structure consists of two types of defects: microdomains based on a single oxygen vacancy with relaxed neighbouring ions and microdomains based on a pair of oxygen vacancies separated by 31/2/2α along <111>. The combined evaluation of neutron and X-ray data shows that the previously published structure of the single vacancy domain has to be modified: All cations next to the oxygen vacancy are most likely zirconium. This modified model leads to good agreement between observed and calculated neutron and X-ray diffraction patterns.

UR - http://www.scopus.com/inward/record.url?scp=0002589998&partnerID=8YFLogxK

U2 - 10.1107/S0108768195007920

DO - 10.1107/S0108768195007920

M3 - Article

AN - SCOPUS:0002589998

SN - 0108-7681

VL - 52

SP - 59

EP - 65

JO - Acta Crystallographica Section B: Structural Science

JF - Acta Crystallographica Section B: Structural Science

IS - 1

ER -

Neutron and X-ray Diffuse Scattering of Calcium-Stabilized Zirconia

Abstract

Access to Document

Other files and links

Fingerprint

Cite this