Negative area compressibility in silver(i) tricyanomethanide

Sarah A. Hodgson; Jasper Adamson; Sarah J. Hunt; Matthew J. Cliffe; Andrew B. Cairns; Amber L. Thompson; Matthew J. Tucker; Nicholas P. Funnell; Andrew L. Goodwin

doi:10.1039/c3cc47032f

Negative area compressibility in silver(i) tricyanomethanide

Sarah A. Hodgson, Jasper Adamson, Sarah J. Hunt, Matthew J. Cliffe, Andrew B. Cairns, Amber L. Thompson, Matthew J. Tucker, Nicholas P. Funnell, Andrew L. Goodwin

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

The molecular framework Ag(tcm) (tcm⁻ = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

Original language	English
Pages (from-to)	5264-5266
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	40
DOIs	https://doi.org/10.1039/c3cc47032f
State	Published - Apr 22 2014
Externally published	Yes

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title = "Negative area compressibility in silver(i) tricyanomethanide",

abstract = "The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.",

author = "Hodgson, \{Sarah A.\} and Jasper Adamson and Hunt, \{Sarah J.\} and Cliffe, \{Matthew J.\} and Cairns, \{Andrew B.\} and Thompson, \{Amber L.\} and Tucker, \{Matthew J.\} and Funnell, \{Nicholas P.\} and Goodwin, \{Andrew L.\}",

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doi = "10.1039/c3cc47032f",

language = "English",

volume = "50",

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AU - Hodgson, Sarah A.

AU - Adamson, Jasper

AU - Hunt, Sarah J.

AU - Cliffe, Matthew J.

AU - Cairns, Andrew B.

AU - Thompson, Amber L.

AU - Tucker, Matthew J.

AU - Funnell, Nicholas P.

AU - Goodwin, Andrew L.

PY - 2014/4/22

Y1 - 2014/4/22

N2 - The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

AB - The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

UR - https://www.scopus.com/pages/publications/84898727738

U2 - 10.1039/c3cc47032f

DO - 10.1039/c3cc47032f

M3 - Article

AN - SCOPUS:84898727738

SN - 1359-7345

VL - 50

SP - 5264

EP - 5266

JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Negative area compressibility in silver(i) tricyanomethanide

Abstract

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