Negative area compressibility in silver(i) tricyanomethanide

Sarah A. Hodgson; Jasper Adamson; Sarah J. Hunt; Matthew J. Cliffe; Andrew B. Cairns; Amber L. Thompson; Matthew J. Tucker; Nicholas P. Funnell; Andrew L. Goodwin

doi:10.1039/c3cc47032f

Negative area compressibility in silver(i) tricyanomethanide

Sarah A. Hodgson
, Jasper Adamson
, Sarah J. Hunt
, Matthew J. Cliffe
, Andrew B. Cairns
, Amber L. Thompson
, Matthew J. Tucker
, Nicholas P. Funnell
, Andrew L. Goodwin

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

The molecular framework Ag(tcm) (tcm⁻ = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

Original language	English
Pages (from-to)	5264-5266
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	40
DOIs	https://doi.org/10.1039/c3cc47032f
State	Published - Apr 22 2014
Externally published	Yes

Access to Document

10.1039/c3cc47032f

Cite this

@article{334a19b69de947e994047b2d64293d1d,

title = "Negative area compressibility in silver(i) tricyanomethanide",

abstract = "The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.",

author = "Hodgson, \{Sarah A.\} and Jasper Adamson and Hunt, \{Sarah J.\} and Cliffe, \{Matthew J.\} and Cairns, \{Andrew B.\} and Thompson, \{Amber L.\} and Tucker, \{Matthew J.\} and Funnell, \{Nicholas P.\} and Goodwin, \{Andrew L.\}",

year = "2014",

month = apr,

day = "22",

doi = "10.1039/c3cc47032f",

language = "English",

volume = "50",

pages = "5264--5266",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "40",

}

TY - JOUR

T1 - Negative area compressibility in silver(i) tricyanomethanide

AU - Hodgson, Sarah A.

AU - Adamson, Jasper

AU - Hunt, Sarah J.

AU - Cliffe, Matthew J.

AU - Cairns, Andrew B.

AU - Thompson, Amber L.

AU - Tucker, Matthew J.

AU - Funnell, Nicholas P.

AU - Goodwin, Andrew L.

PY - 2014/4/22

Y1 - 2014/4/22

N2 - The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

AB - The molecular framework Ag(tcm) (tcm− = tricyanomethanide) expands continuously in two orthogonal directions under hydrostatic compression. The first of its kind, this negative area compressibility behaviour arises from the flattening of honeycomb-like layers during rapid pressure-driven collapse of the interlayer separation.

UR - https://www.scopus.com/pages/publications/84898727738

U2 - 10.1039/c3cc47032f

DO - 10.1039/c3cc47032f

M3 - Article

AN - SCOPUS:84898727738

SN - 1359-7345

VL - 50

SP - 5264

EP - 5266

JO - Chemical Communications

JF - Chemical Communications

IS - 40

ER -

Negative area compressibility in silver(i) tricyanomethanide

Abstract

Access to Document

Other files and links

Fingerprint

Cite this