Nanoscale structure and dynamics in geochemical systems

Andrew G. Stack, Hsiu Wen Wang, David R. Cole

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Neutron scattering is a powerful tool to elucidate the structure and dynamics of systems that are important to geochemists, including ion association in complex aqueous solutions, solvent-exchange reactions at mineral-water interfaces, and reaction and transport of fluids in nanoporous materials. This article focusses on three techniques: neutron diffraction, which can reveal the atomic-level structure of aqueous solutions and solids; quasi-elastic neutron scattering, which measures the diffusional dynamics at mineral-water interfaces; and small-angle neutron scattering, which can show how properties of nanoporous systems change during gas, liquid, and solute imbibition and reaction. The usefulness and applicability of the experimental results are extended by rigorous comparison to computational simulations.

Original languageEnglish
Pages (from-to)169-174
Number of pages6
JournalElements
Volume17
Issue number3
DOIs
StatePublished - Jun 2021

Funding

This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Chemical Sciences, Geosciences, and Biosciences Division.

Keywords

  • Complex aqueous solutions
  • Mineral-water interface
  • Nanopores
  • Neutron scattering

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