Nanocrystalline silicon compacted by spark-plasma sintering: Microstructure and thermoelectric properties

G. Schierning, T. Claudio, R. Theissmann, N. Stein, N. Petermann, André Becker, J. Denker, H. Wiggers, R. P. Hermann, R. Schmechel

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

5 Scopus citations

Abstract

Nanocrystalline bulk silicon samples were fabricated using silicon nanoparticles from the gas phase, applying a spark-plasma sintering process. The mean diameter of the crystalline grains after sintering was 30 nm and smaller, the density above 97 % of that of crystalline silicon. Transmission electron microscopy showed a homogenous nanostructure. The thermal conductivity of such an n-type sample with a nominal doping level of 5×1020 cm -3 was around 11 Wm-1K-1 at room temperature. With Seebeck-coefficient α = -150 μV/K and specific conductivity σ = 290 S cm-1, the resulting efficiency ZT is approximately 0.02.

Original languageEnglish
Title of host publicationThermoelectric Materials 2010 - Growth, Properties, Novel Characterization Methods and Applications
PublisherMaterials Research Society
Pages9-14
Number of pages6
ISBN (Print)9781605112442
DOIs
StatePublished - 2010
Externally publishedYes

Publication series

NameMaterials Research Society Symposium Proceedings
Volume1267
ISSN (Print)0272-9172

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