Abstract
The dilute, rare earth bearing family of RT2 Zn20 (R = rare earth, T = transition metal) intermetallic compounds can be tuned to a nearly ferromagnetic Fermi liquid that is closer to the Stoner limit than Pd (for R = Y, Lu and T = Fe). The submersion of moment bearing rare earths (Gd-Tm) into this highly polarizable matrix gives rise to exceptionally high temperature ferromagnetism (e.g. TC = 86 K for GdFe2 Zn20) for a compound with only one moment bearing ion out of 23 in the formula unit. In addition to this d-shell correlated electron behavior, 4f hybridization gives rise to six, new, Yb-based heavy fermion compounds: YbT2 Zn20 (T = Fe, Ru, Os, Co, Rh, Ir). These half dozen compounds manifest a range of Yb ion degeneracy values (N) for T ∼ TK, ranging from N = 4 - 8. Not only do these compounds offer a clear testing ground for the effects of low temperature degeneracy on the correlated electron state, they also present an exceptionally clear experimental confirmation of the generalized Kadowaki-Woods formalism.
| Original language | English |
|---|---|
| Pages (from-to) | 844-846 |
| Number of pages | 3 |
| Journal | Physica B: Physics of Condensed Matter |
| Volume | 403 |
| Issue number | 5-9 |
| DOIs | |
| State | Published - Apr 1 2008 |
| Externally published | Yes |
Keywords
- Fermi-liquid
- Heavy fermions
- Kadowaki-Woods plot
- Stoner limit
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