Multifunctional polymer composite coatings and adhesives by incorporating cellulose nanomaterials

Lu Wang; Peter V. Kelly; Nihan Ozveren; Xuefeng Zhang; Matthew Korey; Cong Chen; Kai Li; Sunil Bhandari; Halil Tekinalp; Xianhui Zhao; Jinwu Wang; M. Özgür Seydibeyoğlu; Elif Alyamac-Seydibeyoglu; William M. Gramlich; Mehdi Tajvidi; Erin Webb; Soydan Ozcan; Douglas J. Gardner

doi:10.1016/j.matt.2022.11.024

Multifunctional polymer composite coatings and adhesives by incorporating cellulose nanomaterials

Lu Wang, Peter V. Kelly, Nihan Ozveren, Xuefeng Zhang, Matthew Korey, Cong Chen, Kai Li, Sunil Bhandari, Halil Tekinalp, Xianhui Zhao, Jinwu Wang, M. Özgür Seydibeyoğlu, Elif Alyamac-Seydibeyoglu, William M. Gramlich, Mehdi Tajvidi, Erin Webb, Soydan Ozcan, Douglas J. Gardner

Research output: Contribution to journal › Review article › peer-review

32 Scopus citations

Abstract

Regardless of their applications, polymers are still considered mechanically weak and functionally insufficient for certain demanding coating and adhesive uses. To address those issues, nanomaterials have been extensively studied as reinforcing fillers, which have been proven to effectively promote the performance of polymer coatings/adhesives. However, conventional nanofillers are expensive and non-biodegradable. Meanwhile, cellulose nanomaterials (CNMs), a class of nanomaterials produced from biomass feedstocks, can circumvent the drawbacks of conventional nanofillers. This review paper first focuses on the multi-functionalities CNMs bring to polymer coatings, including mechanical reinforcement (wear resistance and hardness enhancement), gas barrier, flame resistance, corrosion resistance, self-healing (controlled-release), optical regulation, self-cleaning/antifouling, and antimicrobial characteristics. Then we discuss the benefits of CNM addition to polymer adhesives, such as mechanical enhancement, curing promotion, volatile organic compound (VOC) suppression, and electrical conductivity. Finally, we provide insights into future research efforts with CNMs. The goal of this paper is to promote the pilot-scale study and commercial use of CNMs as multifunctional additives in green and sustainable polymer composite coating and adhesive formulations.

Original language	English
Pages (from-to)	344-372
Number of pages	29
Journal	Matter
Volume	6
Issue number	2
DOIs	https://doi.org/10.1016/j.matt.2022.11.024
State	Published - Feb 1 2023

Funding

Authors from Oak Ridge National Laboratory (ORNL) are supported by the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office, and Bioenergy Technologies Office, under contract DEAC05-00OR22725 with UT-Battelle LLC. Authors from University of Maine are grateful for the funding support from UT-Battelle LLC with the DOE under contract DEAC05-00OR22725 (subcontract # 4000174848). The authors thank Dr. Mahesh Parit for his contribution to paper structure formation, literature search, and management. Dr. Xuefeng Zhang acknowledges the support from Forest and Wildlife Research Center, Mississippi State University.

Keywords

crystals
dispersion
dye
fibril
intumescence
iridescence
modification
network
template
tortuous path
waterborne

Access to Document

10.1016/j.matt.2022.11.024

Cite this

Wang, L., Kelly, P. V., Ozveren, N., Zhang, X., Korey, M., Chen, C., Li, K., Bhandari, S., Tekinalp, H., Zhao, X., Wang, J., Seydibeyoğlu, M. Ö., Alyamac-Seydibeyoglu, E., Gramlich, W. M., Tajvidi, M., Webb, E., Ozcan, S., & Gardner, D. J. (2023). Multifunctional polymer composite coatings and adhesives by incorporating cellulose nanomaterials. Matter, 6(2), 344-372. https://doi.org/10.1016/j.matt.2022.11.024

@article{48614b1953e74cdc8d01345652369d9d,

title = "Multifunctional polymer composite coatings and adhesives by incorporating cellulose nanomaterials",

abstract = "Regardless of their applications, polymers are still considered mechanically weak and functionally insufficient for certain demanding coating and adhesive uses. To address those issues, nanomaterials have been extensively studied as reinforcing fillers, which have been proven to effectively promote the performance of polymer coatings/adhesives. However, conventional nanofillers are expensive and non-biodegradable. Meanwhile, cellulose nanomaterials (CNMs), a class of nanomaterials produced from biomass feedstocks, can circumvent the drawbacks of conventional nanofillers. This review paper first focuses on the multi-functionalities CNMs bring to polymer coatings, including mechanical reinforcement (wear resistance and hardness enhancement), gas barrier, flame resistance, corrosion resistance, self-healing (controlled-release), optical regulation, self-cleaning/antifouling, and antimicrobial characteristics. Then we discuss the benefits of CNM addition to polymer adhesives, such as mechanical enhancement, curing promotion, volatile organic compound (VOC) suppression, and electrical conductivity. Finally, we provide insights into future research efforts with CNMs. The goal of this paper is to promote the pilot-scale study and commercial use of CNMs as multifunctional additives in green and sustainable polymer composite coating and adhesive formulations.",

keywords = "crystals, dispersion, dye, fibril, intumescence, iridescence, modification, network, template, tortuous path, waterborne",

author = "Lu Wang and Kelly, {Peter V.} and Nihan Ozveren and Xuefeng Zhang and Matthew Korey and Cong Chen and Kai Li and Sunil Bhandari and Halil Tekinalp and Xianhui Zhao and Jinwu Wang and Seydibeyoğlu, {M. {\"O}zg{\"u}r} and Elif Alyamac-Seydibeyoglu and Gramlich, {William M.} and Mehdi Tajvidi and Erin Webb and Soydan Ozcan and Gardner, {Douglas J.}",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Inc.",

year = "2023",

month = feb,

day = "1",

doi = "10.1016/j.matt.2022.11.024",

language = "English",

volume = "6",

pages = "344--372",

journal = "Matter",

issn = "2590-2393",

publisher = "Cell Press",

number = "2",

}

Wang, L, Kelly, PV, Ozveren, N, Zhang, X, Korey, M, Chen, C, Li, K, Bhandari, S, Tekinalp, H, Zhao, X, Wang, J, Seydibeyoğlu, MÖ, Alyamac-Seydibeyoglu, E, Gramlich, WM, Tajvidi, M, Webb, E , Ozcan, S & Gardner, DJ 2023, 'Multifunctional polymer composite coatings and adhesives by incorporating cellulose nanomaterials', Matter, vol. 6, no. 2, pp. 344-372. https://doi.org/10.1016/j.matt.2022.11.024

TY - JOUR

T1 - Multifunctional polymer composite coatings and adhesives by incorporating cellulose nanomaterials

AU - Wang, Lu

AU - Kelly, Peter V.

AU - Ozveren, Nihan

AU - Zhang, Xuefeng

AU - Korey, Matthew

AU - Chen, Cong

AU - Li, Kai

AU - Bhandari, Sunil

AU - Tekinalp, Halil

AU - Zhao, Xianhui

AU - Wang, Jinwu

AU - Seydibeyoğlu, M. Özgür

AU - Alyamac-Seydibeyoglu, Elif

AU - Gramlich, William M.

AU - Tajvidi, Mehdi

AU - Webb, Erin

AU - Ozcan, Soydan

AU - Gardner, Douglas J.

PY - 2023/2/1

Y1 - 2023/2/1

N2 - Regardless of their applications, polymers are still considered mechanically weak and functionally insufficient for certain demanding coating and adhesive uses. To address those issues, nanomaterials have been extensively studied as reinforcing fillers, which have been proven to effectively promote the performance of polymer coatings/adhesives. However, conventional nanofillers are expensive and non-biodegradable. Meanwhile, cellulose nanomaterials (CNMs), a class of nanomaterials produced from biomass feedstocks, can circumvent the drawbacks of conventional nanofillers. This review paper first focuses on the multi-functionalities CNMs bring to polymer coatings, including mechanical reinforcement (wear resistance and hardness enhancement), gas barrier, flame resistance, corrosion resistance, self-healing (controlled-release), optical regulation, self-cleaning/antifouling, and antimicrobial characteristics. Then we discuss the benefits of CNM addition to polymer adhesives, such as mechanical enhancement, curing promotion, volatile organic compound (VOC) suppression, and electrical conductivity. Finally, we provide insights into future research efforts with CNMs. The goal of this paper is to promote the pilot-scale study and commercial use of CNMs as multifunctional additives in green and sustainable polymer composite coating and adhesive formulations.

AB - Regardless of their applications, polymers are still considered mechanically weak and functionally insufficient for certain demanding coating and adhesive uses. To address those issues, nanomaterials have been extensively studied as reinforcing fillers, which have been proven to effectively promote the performance of polymer coatings/adhesives. However, conventional nanofillers are expensive and non-biodegradable. Meanwhile, cellulose nanomaterials (CNMs), a class of nanomaterials produced from biomass feedstocks, can circumvent the drawbacks of conventional nanofillers. This review paper first focuses on the multi-functionalities CNMs bring to polymer coatings, including mechanical reinforcement (wear resistance and hardness enhancement), gas barrier, flame resistance, corrosion resistance, self-healing (controlled-release), optical regulation, self-cleaning/antifouling, and antimicrobial characteristics. Then we discuss the benefits of CNM addition to polymer adhesives, such as mechanical enhancement, curing promotion, volatile organic compound (VOC) suppression, and electrical conductivity. Finally, we provide insights into future research efforts with CNMs. The goal of this paper is to promote the pilot-scale study and commercial use of CNMs as multifunctional additives in green and sustainable polymer composite coating and adhesive formulations.

KW - crystals

KW - dispersion

KW - dye

KW - fibril

KW - intumescence

KW - iridescence

KW - modification

KW - network

KW - template

KW - tortuous path

KW - waterborne

UR - http://www.scopus.com/inward/record.url?scp=85147797943&partnerID=8YFLogxK

U2 - 10.1016/j.matt.2022.11.024

DO - 10.1016/j.matt.2022.11.024

M3 - Review article

AN - SCOPUS:85147797943

SN - 2590-2393

VL - 6

SP - 344

EP - 372

JO - Matter

JF - Matter

IS - 2

ER -

Multifunctional polymer composite coatings and adhesives by incorporating cellulose nanomaterials

Abstract

Funding

Keywords

Access to Document

Other files and links

Fingerprint

Cite this