Multi-purpose cellulosic ionogels

Chip J. Smith, Durgesh V. Wagle, Hugh M. O'Neill, Barbara R. Evans, Sheila N. Baker, Gary A. Baker

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

2 Scopus citations

Abstract

The immobilization of ionic liquid into a support matrix for practical applications is frequently inefficient (i.e., low loading capacity) or otherwise compromises the attractive properties of the sequestered ionic liquid phase. One promising strategy for ionic liquid immobilization entails the formation of an ionogel, although reported ionogels sometimes suffer from solvent/matrix incompatibility, limited liquid loading capacity, and the development of optical opacity or physical embrittlement. In this chapter, we introduce a straightforward procedure for preparing bacterial cellulose ionogels (BCIGs) using an ethanol co-solvent exchange process to achieve ionic liquid loadings of up to 99 weight percent. The resulting ionogels are transparent, stable, flexible, size- and shape-tunable, and can host a range of chemistries toward multi-purpose applications.

Original languageEnglish
Title of host publicationIonic Liquids
Subtitle of host publicationCurrent State and Future Directions
EditorsAaron M. Scurto, Mark B. Shiflett
PublisherAmerican Chemical Society
Pages143-155
Number of pages13
ISBN (Electronic)9780841232129
DOIs
StatePublished - 2017

Publication series

NameACS Symposium Series
Volume1250
ISSN (Print)0097-6156
ISSN (Electronic)1947-5918

Funding

Financial support from Research Cooporation for Science Advancement to G.A.B. is gratefully acknowledged. C.J.S. was supported by an IGERT trainee fellowship at the Univerisity of Missouri (NSF Grant No. DGE-1069091).

FundersFunder number
IGERT
Univerisity of Missouri
National Science Foundation
Research Corporation for Science Advancement

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