Abstract
Two A356 aluminum alloys (Al–Si–Mg), one with 0.09 wt.% Fe and one with 0.91 wt.% Fe, were cast in a graphite mold with simultaneous local ultrasonic processing to refine the as-cast microstructure. Ultrasonication during casting transformed the morphology of primary Al grains from dendritic (~ 140–290 microns in size) to globular (~ 33–36 microns in size). The alloy with high Fe exhibited globular grains at distances up to 45 mm away from the ultrasound probe, while the alloy with low Fe exhibited globular grains at distances only up to 6 mm away from the ultrasound probe. Near the location of the ultrasound probe (< 2 mm away), a second non-dendritic microstructural morphology was observed with fine aluminum grains (~ 9–25 microns in size). This unique fine-grained morphology has not been previously reported, contains a greater area fraction of Si relative to the globular microstructure, and may be a large, fully eutectic region. Ultrasonication during casting also transformed the morphology of the β-Al5FeSi phase particles (which are deleterious to the strength and ductility of the alloy) in the high Fe alloy from needle-like to rectangular, which could enable the greater use of secondary Al alloys. Thermodynamic simulations conducted to calculate the solidification paths of the two alloys studied predict that the β-Al5FeSi phase begins to form earlier in the alloy with high Fe. Data suggest that the β-Al5FeSi phase (which is more abundant in alloys with high Fe content) may enhance ultrasonically-induced grain refinement.
Original language | English |
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Pages (from-to) | 17340-17361 |
Number of pages | 22 |
Journal | Journal of Materials Science |
Volume | 58 |
Issue number | 45 |
DOIs | |
State | Published - Dec 2023 |
Funding
The project was funded by the Department of Energy Vehicle Technologies Office as part of the Lightweight Metals Core Program. This research was conducted at PNNL, under Contract No. DE-AC05-76L01830 with the U.S. Department of Energy and UT-Battelle, LLC, under Contract No. DE-AC05-00OR22725 with the U.S. Department of Energy. The authors thank Mr. David Weiss at Eck Industries for providing the alloys for this work and technical discussions. The authors also thank Jens Darsell, Jon Helgeland, Anthony Guzman, Michael Blazon, and Nathan Canfield of Pacific Northwest National Laboratory for their technical assistance.