Microscopic mechanisms of electric-field-induced alignment of block copolymer microdomains

A. Böker, H. Elbs, H. Hänsel, A. Knoll, S. Ludwigs, H. Zettl, V. Urban, V. Abetz, A. H. Müller, G. Krausch

Research output: Contribution to journalArticlepeer-review

124 Scopus citations

Abstract

The microscopic mechanisms of electric field induced alignment of block copolymer microdomains was discussed. Grain boundary migration and rotation of grains were two distinct processes revealed using time-resolved synchrotron small-angle x-ray scattering. Two distinct microscopic mechanisms dominated the reorientation process in a certain regime of polymer concentration and temperature. The integrated scattering intensity was found to drop during the initial stage of the reorientation process and increased at later times.

Original languageEnglish
Article number135502
Pages (from-to)1355021-1355024
Number of pages4
JournalPhysical Review Letters
Volume89
Issue number13
DOIs
StatePublished - Sep 23 2002
Externally publishedYes

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