Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

Banglin Chen; Yanyan Ji; Ming Xue; Frank R. Fronczek; Eric J. Hurtado; Jalal U. Mondal; Chengdu Liang; Sheng Dai

doi:10.1021/ic8004008

Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

Banglin Chen, Yanyan Ji, Ming Xue, Frank R. Fronczek, Eric J. Hurtado, Jalal U. Mondal, Chengdu Liang, Sheng Dai

Chemical Sciences Division

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) _0.5·0.55H₂O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 Å, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.

Original language	English
Pages (from-to)	5543-5545
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	13
DOIs	https://doi.org/10.1021/ic8004008
State	Published - Jul 7 2008

Access to Document

10.1021/ic8004008

Cite this

@article{e40196308dc5488683675959ccbf7200,

title = "Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol",

abstract = "A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) 0.5·0.55H2O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 {\AA}, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.",

author = "Banglin Chen and Yanyan Ji and Ming Xue and Fronczek, \{Frank R.\} and Hurtado, \{Eric J.\} and Mondal, \{Jalal U.\} and Chengdu Liang and Sheng Dai",

year = "2008",

month = jul,

day = "7",

doi = "10.1021/ic8004008",

language = "English",

volume = "47",

pages = "5543--5545",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

AU - Chen, Banglin

AU - Ji, Yanyan

AU - Xue, Ming

AU - Fronczek, Frank R.

AU - Hurtado, Eric J.

AU - Mondal, Jalal U.

AU - Liang, Chengdu

AU - Dai, Sheng

PY - 2008/7/7

Y1 - 2008/7/7

N2 - A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) 0.5·0.55H2O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 Å, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.

AB - A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) 0.5·0.55H2O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 Å, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.

UR - https://www.scopus.com/pages/publications/47949090840

U2 - 10.1021/ic8004008

DO - 10.1021/ic8004008

M3 - Article

AN - SCOPUS:47949090840

SN - 0020-1669

VL - 47

SP - 5543

EP - 5545

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

Abstract

Access to Document

Other files and links

Fingerprint

Cite this