Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

Banglin Chen; Yanyan Ji; Ming Xue; Frank R. Fronczek; Eric J. Hurtado; Jalal U. Mondal; Chengdu Liang; Sheng Dai

doi:10.1021/ic8004008

Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

Banglin Chen
, Yanyan Ji
, Ming Xue
, Frank R. Fronczek
, Eric J. Hurtado
, Jalal U. Mondal
, Chengdu Liang
, Sheng Dai

Chemical Sciences Division

Research output: Contribution to journal › Article › peer-review

95 Scopus citations

Abstract

A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) _0.5·0.55H₂O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 Å, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.

Original language	English
Pages (from-to)	5543-5545
Number of pages	3
Journal	Inorganic Chemistry
Volume	47
Issue number	13
DOIs	https://doi.org/10.1021/ic8004008
State	Published - Jul 7 2008

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@article{e40196308dc5488683675959ccbf7200,

title = "Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol",

abstract = "A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) 0.5·0.55H2O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 {\AA}, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.",

author = "Banglin Chen and Yanyan Ji and Ming Xue and Fronczek, \{Frank R.\} and Hurtado, \{Eric J.\} and Mondal, \{Jalal U.\} and Chengdu Liang and Sheng Dai",

year = "2008",

month = jul,

day = "7",

doi = "10.1021/ic8004008",

language = "English",

volume = "47",

pages = "5543--5545",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

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T1 - Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

AU - Chen, Banglin

AU - Ji, Yanyan

AU - Xue, Ming

AU - Fronczek, Frank R.

AU - Hurtado, Eric J.

AU - Mondal, Jalal U.

AU - Liang, Chengdu

AU - Dai, Sheng

PY - 2008/7/7

Y1 - 2008/7/7

N2 - A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) 0.5·0.55H2O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 Å, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.

AB - A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4′-Bipy) 0.5·0.55H2O (R-GLA-Me = R-2-methylglutarate, 4,4′-Bipy = 4,4′-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 Å, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.

UR - https://www.scopus.com/pages/publications/47949090840

U2 - 10.1021/ic8004008

DO - 10.1021/ic8004008

M3 - Article

AN - SCOPUS:47949090840

SN - 0020-1669

VL - 47

SP - 5543

EP - 5545

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 13

ER -

Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

Abstract

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