Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO2 conversion

Xiaoxiao Yu; Zhenzhen Yang; Shien Guo; Zhenghui Liu; Hongye Zhang; Bo Yu; Yanfei Zhao; Zhimin Liu

doi:10.1039/c8cc03346c

Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO₂ conversion

Xiaoxiao Yu
, Zhenzhen Yang
, Shien Guo
, Zhenghui Liu
, Hongye Zhang
, Bo Yu
, Yanfei Zhao
, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO₂/H₂ at 100 °C, affording a series of formamides in high yields.

Original language	English
Pages (from-to)	7633-7636
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	55
DOIs	https://doi.org/10.1039/c8cc03346c
State	Published - 2018
Externally published	Yes

Funding

We thank the National Natural Science Foundation of China (No. 21673256 and 21533011), and the Chinese Academy of Sciences (QYZDY-SSW-SLH013-2) for financial support.

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10.1039/c8cc03346c

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title = "Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO2 conversion",

abstract = "A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO2/H2 at 100 °C, affording a series of formamides in high yields.",

author = "Xiaoxiao Yu and Zhenzhen Yang and Shien Guo and Zhenghui Liu and Hongye Zhang and Bo Yu and Yanfei Zhao and Zhimin Liu",

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T1 - Mesoporous imine-based organic polymer

T2 - catalyst-free synthesis in water and application in CO2 conversion

AU - Yu, Xiaoxiao

AU - Yang, Zhenzhen

AU - Guo, Shien

AU - Liu, Zhenghui

AU - Zhang, Hongye

AU - Yu, Bo

AU - Zhao, Yanfei

AU - Liu, Zhimin

PY - 2018

Y1 - 2018

N2 - A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO2/H2 at 100 °C, affording a series of formamides in high yields.

AB - A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO2/H2 at 100 °C, affording a series of formamides in high yields.

UR - https://www.scopus.com/pages/publications/85049640182

U2 - 10.1039/c8cc03346c

DO - 10.1039/c8cc03346c

M3 - Article

C2 - 29931000

AN - SCOPUS:85049640182

SN - 1359-7345

VL - 54

SP - 7633

EP - 7636

JO - Chemical Communications

JF - Chemical Communications

IS - 55

ER -

Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO₂ conversion

Abstract

Funding

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