Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO2 conversion

Xiaoxiao Yu; Zhenzhen Yang; Shien Guo; Zhenghui Liu; Hongye Zhang; Bo Yu; Yanfei Zhao; Zhimin Liu

doi:10.1039/c8cc03346c

Mesoporous imine-based organic polymer: catalyst-free synthesis in water and application in CO₂ conversion

Xiaoxiao Yu, Zhenzhen Yang, Shien Guo, Zhenghui Liu, Hongye Zhang, Bo Yu, Yanfei Zhao, Zhimin Liu

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO₂/H₂ at 100 °C, affording a series of formamides in high yields.

Original language	English
Pages (from-to)	7633-7636
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	55
DOIs	https://doi.org/10.1039/c8cc03346c
State	Published - 2018
Externally published	Yes

Funding

We thank the National Natural Science Foundation of China (No. 21673256 and 21533011), and the Chinese Academy of Sciences (QYZDY-SSW-SLH013-2) for financial support.

Funders	Funder number
National Natural Science Foundation of China	21673256, 21533011
Chinese Academy of Sciences	QYZDY-SSW-SLH013-2

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1039/c8cc03346c

Cite this

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abstract = "A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO2/H2 at 100 °C, affording a series of formamides in high yields.",

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AU - Yu, Xiaoxiao

AU - Yang, Zhenzhen

AU - Guo, Shien

AU - Liu, Zhenghui

AU - Zhang, Hongye

AU - Yu, Bo

AU - Zhao, Yanfei

AU - Liu, Zhimin

PY - 2018

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AB - A mesoporous imine-functionalized organic polymer (Imine-POP) was prepared based on the reaction of an aryl ammonium salt with an aromatic aldehyde in water without any catalyst and template. The Pd coordinated Imine-POP exhibited high catalytic activity for the N-formylation of amines with CO2/H2 at 100 °C, affording a series of formamides in high yields.

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DO - 10.1039/c8cc03346c

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