Measurement of exchange current density of LaCl3 in LiCl-KCl eutectic salt

Hunter B. Andrews; Supathorn Phongikaroon

Measurement of exchange current density of LaCl₃ in LiCl-KCl eutectic salt

Hunter B. Andrews, Supathorn Phongikaroon

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Three electrochemical methods for finding the exchange current density of materials in molten salt (cyclic voltammetry (CV), linear polarization (LP), and Tafel) were compared to investigate which would provide the optimal near real-time approximation for exchange current density. LaCl₃ was used as the material in a ternary salt system (LaCl₃-LiCl-KCl) and a quaternary salt system (LaCl₃-GdCl₃-LiCl-KCl). Each technique was applied at temperatures ranging from 723K - 798K, as well as various scan rates. The resulting exchange current density values showed CV, LP, and Tafel having mean standard deviations of 0.0019 A cm^-2, 0.0039 A cm^-2, and 0.1065 A cm^-2, respectively. The data showed that CV was the superior method due to its faster scan rate along with possessing the lowest deviation.

Original language	English
Title of host publication	2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings
Publisher	International Congress on Advances in Nuclear Power Plants, ICAPP
ISBN (Electronic)	9784890471676
State	Published - 2017
Externally published	Yes
Event	2017 International Congress on Advances in Nuclear Power Plants: A New Paradigm in Nuclear Power Safety, ICAPP 2017 - Fukui and Kyoto, Japan Duration: Apr 24 2017 → Apr 28 2017

Publication series

Name	2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings

Conference

Conference	2017 International Congress on Advances in Nuclear Power Plants: A New Paradigm in Nuclear Power Safety, ICAPP 2017
Country/Territory	Japan
City	Fukui and Kyoto
Period	04/24/17 → 04/28/17

Funding

This study is being performed using funding received from the DOE Office of Nuclear Energy’s Nuclear Energy University Programs (NEUP) in collaboration with the University of Utah and Ohio State University (NEUP-14-6542).

Funders	Funder number
DOE Office of Nuclear Energy
Nuclear Energy University Programs
University of Utah and Ohio State University	NEUP-14-6542

Cite this

Andrews, H. B., & Phongikaroon, S. (2017). Measurement of exchange current density of LaCl₃ in LiCl-KCl eutectic salt. In 2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings (2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings). International Congress on Advances in Nuclear Power Plants, ICAPP.

Andrews, Hunter B. ; Phongikaroon, Supathorn. / Measurement of exchange current density of LaCl₃ in LiCl-KCl eutectic salt. 2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings. International Congress on Advances in Nuclear Power Plants, ICAPP, 2017. (2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings).

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title = "Measurement of exchange current density of LaCl3 in LiCl-KCl eutectic salt",

abstract = "Three electrochemical methods for finding the exchange current density of materials in molten salt (cyclic voltammetry (CV), linear polarization (LP), and Tafel) were compared to investigate which would provide the optimal near real-time approximation for exchange current density. LaCl3 was used as the material in a ternary salt system (LaCl3-LiCl-KCl) and a quaternary salt system (LaCl3-GdCl3-LiCl-KCl). Each technique was applied at temperatures ranging from 723K - 798K, as well as various scan rates. The resulting exchange current density values showed CV, LP, and Tafel having mean standard deviations of 0.0019 A cm-2, 0.0039 A cm-2, and 0.1065 A cm-2, respectively. The data showed that CV was the superior method due to its faster scan rate along with possessing the lowest deviation.",

author = "Andrews, {Hunter B.} and Supathorn Phongikaroon",

year = "2017",

language = "English",

series = "2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings",

publisher = "International Congress on Advances in Nuclear Power Plants, ICAPP",

booktitle = "2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings",

note = "2017 International Congress on Advances in Nuclear Power Plants: A New Paradigm in Nuclear Power Safety, ICAPP 2017 ; Conference date: 24-04-2017 Through 28-04-2017",

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Andrews, HB & Phongikaroon, S 2017, Measurement of exchange current density of LaCl₃ in LiCl-KCl eutectic salt. in 2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings. 2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings, International Congress on Advances in Nuclear Power Plants, ICAPP, 2017 International Congress on Advances in Nuclear Power Plants: A New Paradigm in Nuclear Power Safety, ICAPP 2017, Fukui and Kyoto, Japan, 04/24/17.

Measurement of exchange current density of LaCl₃ in LiCl-KCl eutectic salt. / Andrews, Hunter B.; Phongikaroon, Supathorn.
2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings. International Congress on Advances in Nuclear Power Plants, ICAPP, 2017. (2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Measurement of exchange current density of LaCl3 in LiCl-KCl eutectic salt

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AU - Phongikaroon, Supathorn

PY - 2017

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N2 - Three electrochemical methods for finding the exchange current density of materials in molten salt (cyclic voltammetry (CV), linear polarization (LP), and Tafel) were compared to investigate which would provide the optimal near real-time approximation for exchange current density. LaCl3 was used as the material in a ternary salt system (LaCl3-LiCl-KCl) and a quaternary salt system (LaCl3-GdCl3-LiCl-KCl). Each technique was applied at temperatures ranging from 723K - 798K, as well as various scan rates. The resulting exchange current density values showed CV, LP, and Tafel having mean standard deviations of 0.0019 A cm-2, 0.0039 A cm-2, and 0.1065 A cm-2, respectively. The data showed that CV was the superior method due to its faster scan rate along with possessing the lowest deviation.

AB - Three electrochemical methods for finding the exchange current density of materials in molten salt (cyclic voltammetry (CV), linear polarization (LP), and Tafel) were compared to investigate which would provide the optimal near real-time approximation for exchange current density. LaCl3 was used as the material in a ternary salt system (LaCl3-LiCl-KCl) and a quaternary salt system (LaCl3-GdCl3-LiCl-KCl). Each technique was applied at temperatures ranging from 723K - 798K, as well as various scan rates. The resulting exchange current density values showed CV, LP, and Tafel having mean standard deviations of 0.0019 A cm-2, 0.0039 A cm-2, and 0.1065 A cm-2, respectively. The data showed that CV was the superior method due to its faster scan rate along with possessing the lowest deviation.

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BT - 2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings

PB - International Congress on Advances in Nuclear Power Plants, ICAPP

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Y2 - 24 April 2017 through 28 April 2017

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Andrews HB, Phongikaroon S. Measurement of exchange current density of LaCl₃ in LiCl-KCl eutectic salt. In 2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings. International Congress on Advances in Nuclear Power Plants, ICAPP. 2017. (2017 International Congress on Advances in Nuclear Power Plants, ICAPP 2017 - A New Paradigm in Nuclear Power Safety, Proceedings).