Mask-patterned wet etching of thin titanium liquid/gas diffusion layers for a PEMEC

Jingke Mo, Stuart M. Steen, Scott T. Retterer, David A. Cullen, Alexander Terekhov, Feng Yuan Zhang

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

28 Scopus citations

Abstract

A liquid/gas diffusion layer in a proton exchange membrane electrolyzer cell is located between the catalyst layer and flow field/current distributors, which is expected to transport electrons, heat, and reactants/products to and from the catalyst layers. In addition, conventional materials, which are typically used in PEM fuel cells, are unsuitable due to the high ohmic potential and highly oxidative environment of the oxygen electrode. In this study, a set of well-tunable and titanium thin-film liquid/gas diffusion layer with different thicknesses and porosities are designed and fabricated by using photolithography and mask-patterned wet etching techniques. The effect of mask pore size as well as different etchants on the etch rate and pore morphology of titanium is investigated. Ex-situ analysis is also performed to characterize the morphological features of the liquid/gas diffusion layer post etching. From the results of the fabrication and analysis, new methods for the fabrication of well-tunable thin film liquid/gas diffusion layers is detailed.

Original languageEnglish
Title of host publicationMaterials for Low Temperature Electrochemical Systems 2
EditorsM. Shao, P. N. Pintauro
PublisherElectrochemical Society Inc.
Pages3-10
Number of pages8
Edition24
ISBN (Electronic)9781607686477
DOIs
StatePublished - 2015
EventSymposium on Materials for Low Temperature Electrochemical Systems 2 - 227th ECS Meeting - Chicago, United States
Duration: May 24 2015May 28 2015

Publication series

NameECS Transactions
Number24
Volume66
ISSN (Print)1938-6737
ISSN (Electronic)1938-5862

Conference

ConferenceSymposium on Materials for Low Temperature Electrochemical Systems 2 - 227th ECS Meeting
Country/TerritoryUnited States
CityChicago
Period05/24/1505/28/15

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