Magnetic properties of the antiferromagnetic S = 1 spin chain system [Ni(C4H12N2)2(μ-N 3)]n(ClO4)n

B. H. Ward; G. E. Granroth; D. R. Talham; M. W. Meisel

doi:10.1016/S0304-8853(97)00371-5

Magnetic properties of the antiferromagnetic S = 1 spin chain system [Ni(C₄H₁₂N₂)₂(μ-N ₃)]_n(ClO₄)_n

B. H. Ward, G. E. Granroth, D. R. Talham, M. W. Meisel

Direct Geometry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The magnetic properties of powder and oriented single-crystal samples of [Ni(1,2-diamino-2-methylpropane)₂(μ-N₃)] _n(ClO₄)_n have been measured down to 2 K in fields up to 5 T. The data obtained with oriented crystals suggest an antiferromagnetic ordering occurs near 10 K. A theoretical fit of the data for T > 15 K yields values for the nearest-neighbor spin exchange interaction J ≈ 24 K, when the single-ion anisotropy D = 0.

Original language	English
Pages (from-to)	661-662
Number of pages	2
Journal	Journal of Magnetism and Magnetic Materials
Volume	177-181
Issue number	PART 1
DOIs	https://doi.org/10.1016/S0304-8853(97)00371-5
State	Published - Jan 1998

Funding

We have benefited from conversations with F. Sharifi, Th. Jolicoeur, A. Feher, M. Orendfi6 and J. Cernfik. This work was supported in part by NSF Grants DMR-9530453 (DRT) and DMR-9200671 (MWM).

Keywords

Antiferromagnets - one dimensional
Heisenberg antiferromagnet
Magnetization measurements
Susceptibility

Access to Document

10.1016/S0304-8853(97)00371-5

Cite this

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title = "Magnetic properties of the antiferromagnetic S = 1 spin chain system [Ni(C4H12N2)2(μ-N 3)]n(ClO4)n",

abstract = "The magnetic properties of powder and oriented single-crystal samples of [Ni(1,2-diamino-2-methylpropane)2(μ-N3)] n(ClO4)n have been measured down to 2 K in fields up to 5 T. The data obtained with oriented crystals suggest an antiferromagnetic ordering occurs near 10 K. A theoretical fit of the data for T > 15 K yields values for the nearest-neighbor spin exchange interaction J ≈ 24 K, when the single-ion anisotropy D = 0.",

keywords = "Antiferromagnets - one dimensional, Heisenberg antiferromagnet, Magnetization measurements, Susceptibility",

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AU - Granroth, G. E.

AU - Talham, D. R.

AU - Meisel, M. W.

PY - 1998/1

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N2 - The magnetic properties of powder and oriented single-crystal samples of [Ni(1,2-diamino-2-methylpropane)2(μ-N3)] n(ClO4)n have been measured down to 2 K in fields up to 5 T. The data obtained with oriented crystals suggest an antiferromagnetic ordering occurs near 10 K. A theoretical fit of the data for T > 15 K yields values for the nearest-neighbor spin exchange interaction J ≈ 24 K, when the single-ion anisotropy D = 0.

AB - The magnetic properties of powder and oriented single-crystal samples of [Ni(1,2-diamino-2-methylpropane)2(μ-N3)] n(ClO4)n have been measured down to 2 K in fields up to 5 T. The data obtained with oriented crystals suggest an antiferromagnetic ordering occurs near 10 K. A theoretical fit of the data for T > 15 K yields values for the nearest-neighbor spin exchange interaction J ≈ 24 K, when the single-ion anisotropy D = 0.

KW - Antiferromagnets - one dimensional

KW - Heisenberg antiferromagnet

KW - Magnetization measurements

KW - Susceptibility

UR - https://www.scopus.com/pages/publications/0031677740

U2 - 10.1016/S0304-8853(97)00371-5

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JF - Journal of Magnetism and Magnetic Materials

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