Magnetic neutron scattering of thermally quenched K-Co-Fe Prussian blue analog photomagnet

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Abstract

Magnetic order in the thermally quenched photomagnetic Prussian blue analog coordination polymer K 0.27Co[Fe(CN) 6] 0.73[D 2O 6] 0.27•1.42D 2O has been studied down to 4 K with unpolarized and polarized neutron powder diffraction as a function of applied magnetic field. Analysis of the data allows the on-site coherent magnetization of the Co and Fe spins to be established. Specifically, magnetic fields of 1 and 4 T induce moments parallel to the applied field, and the sample behaves as a ferromagnet with a wandering axis.

Original languageEnglish
Article number054431
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume86
Issue number5
DOIs
StatePublished - Aug 20 2012

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