Magnetic base catalysts for the chemical fixation of carbon dioxide to quinazoline-2,4(1H,3H)-diones

Ya Nan Zhao; Bing Yu; Zhen Zhen Yang; Liang Nian He

doi:10.1039/c4ra03659j

Magnetic base catalysts for the chemical fixation of carbon dioxide to quinazoline-2,4(1H,3H)-diones

Ya Nan Zhao, Bing Yu, Zhen Zhen Yang, Liang Nian He

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Organic superbase-functionalized magnetic Fe₃O₄ was investigated to catalyze the fixation of CO₂ with 2-aminobenzonitriles, resulting in the synthesis of quinazoline-2,4(1H,3H)- diones. After optimization of various reaction parameters such as reaction time, solvent, temperature and CO₂ pressure, 1,5,7-triazabicyclo[4.4.0] dec-5-ene (TBD)-functionalized Fe₃O₄ was proven to be an efficient and recyclable magnetic heterogeneous catalyst for the synthesis of various quinazoline-2,4(1H,3H)-diones in reasonable yields (66-93%), and it could be recovered using an external magnetic field.

Original language	English
Pages (from-to)	28941-28946
Number of pages	6
Journal	RSC Advances
Volume	4
Issue number	55
DOIs	https://doi.org/10.1039/c4ra03659j
State	Published - 2014
Externally published	Yes

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title = "Magnetic base catalysts for the chemical fixation of carbon dioxide to quinazoline-2,4(1H,3H)-diones",

abstract = "Organic superbase-functionalized magnetic Fe3O4 was investigated to catalyze the fixation of CO2 with 2-aminobenzonitriles, resulting in the synthesis of quinazoline-2,4(1H,3H)- diones. After optimization of various reaction parameters such as reaction time, solvent, temperature and CO2 pressure, 1,5,7-triazabicyclo[4.4.0] dec-5-ene (TBD)-functionalized Fe3O4 was proven to be an efficient and recyclable magnetic heterogeneous catalyst for the synthesis of various quinazoline-2,4(1H,3H)-diones in reasonable yields (66-93\%), and it could be recovered using an external magnetic field.",

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year = "2014",

doi = "10.1039/c4ra03659j",

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volume = "4",

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journal = "RSC Advances",

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publisher = "Royal Society of Chemistry",

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T1 - Magnetic base catalysts for the chemical fixation of carbon dioxide to quinazoline-2,4(1H,3H)-diones

AU - Zhao, Ya Nan

AU - Yu, Bing

AU - Yang, Zhen Zhen

AU - He, Liang Nian

PY - 2014

Y1 - 2014

N2 - Organic superbase-functionalized magnetic Fe3O4 was investigated to catalyze the fixation of CO2 with 2-aminobenzonitriles, resulting in the synthesis of quinazoline-2,4(1H,3H)- diones. After optimization of various reaction parameters such as reaction time, solvent, temperature and CO2 pressure, 1,5,7-triazabicyclo[4.4.0] dec-5-ene (TBD)-functionalized Fe3O4 was proven to be an efficient and recyclable magnetic heterogeneous catalyst for the synthesis of various quinazoline-2,4(1H,3H)-diones in reasonable yields (66-93%), and it could be recovered using an external magnetic field.

AB - Organic superbase-functionalized magnetic Fe3O4 was investigated to catalyze the fixation of CO2 with 2-aminobenzonitriles, resulting in the synthesis of quinazoline-2,4(1H,3H)- diones. After optimization of various reaction parameters such as reaction time, solvent, temperature and CO2 pressure, 1,5,7-triazabicyclo[4.4.0] dec-5-ene (TBD)-functionalized Fe3O4 was proven to be an efficient and recyclable magnetic heterogeneous catalyst for the synthesis of various quinazoline-2,4(1H,3H)-diones in reasonable yields (66-93%), and it could be recovered using an external magnetic field.

UR - https://www.scopus.com/pages/publications/84904097847

U2 - 10.1039/c4ra03659j

DO - 10.1039/c4ra03659j

M3 - Article

AN - SCOPUS:84904097847

SN - 2046-2069

VL - 4

SP - 28941

EP - 28946

JO - RSC Advances

JF - RSC Advances

IS - 55

ER -

Magnetic base catalysts for the chemical fixation of carbon dioxide to quinazoline-2,4(1H,3H)-diones

Abstract

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