Magnetic and crystal structures of Sr2IrO4: A neutron diffraction study

Feng Ye, Songxue Chi, Bryan C. Chakoumakos, Jaime A. Fernandez-Baca, Tongfei Qi, G. Cao

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195 Scopus citations

Abstract

We report a single-crystal neutron diffraction study of the layered Sr 2IrO4. This work unambiguously determines the magnetic structure of the system and reveals that the spin orientation rigidly tracks the staggered rotation of the IrO6 octahedra in Sr2IrO 4. The long-range antiferromagnetic order has a canted spin configuration with an ordered moment of 0.208(3) μB/Ir site within the basal plane; a detailed examination of the spin canting yields 0.202(3) and 0.049(2) μB/site for the a axis and the b axis, respectively. It is intriguing that forbidden nuclear reflections of space group I4 1/acd are also observed in a wide temperature range from 4 K to 600 K, which suggests a reduced crystal structure symmetry. This neutron-scattering work provides a direct, well-refined experimental characterization of the magnetic and crystal structures that are crucial to the understanding of the unconventional magnetism exhibited in this unusual magnetic insulator.

Original languageEnglish
Article number140406
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume87
Issue number14
DOIs
StatePublished - Apr 22 2013

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