Macrocycle ring expansion by double Stevens rearrangement

Keisha K. Ellis-Holder; Brian P. Peppers; Andrei Yu Kovalevsky; Steven T. Diver

doi:10.1021/ol060657a

Macrocycle ring expansion by double Stevens rearrangement

Keisha K. Ellis-Holder
, Brian P. Peppers
, Andrei Yu Kovalevsky
, Steven T. Diver

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

New benzimidazolidinone cyclophanes were synthesized through a double Stevens rearrangement employed as a ring expansion technique. Para-substituted heterophanes underwent efficient rearrangement. Meta-substituted heterophanes were also prepared. Structure analyses of the new cyclophanes are also provided.

Original language	English
Pages (from-to)	2511-2514
Number of pages	4
Journal	Organic Letters
Volume	8
Issue number	12
DOIs	https://doi.org/10.1021/ol060657a
State	Published - Jun 8 2006
Externally published	Yes

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@article{55f3ac8215ad44c0955e00c0b5a01e83,

title = "Macrocycle ring expansion by double Stevens rearrangement",

abstract = "New benzimidazolidinone cyclophanes were synthesized through a double Stevens rearrangement employed as a ring expansion technique. Para-substituted heterophanes underwent efficient rearrangement. Meta-substituted heterophanes were also prepared. Structure analyses of the new cyclophanes are also provided.",

author = "Ellis-Holder, \{Keisha K.\} and Peppers, \{Brian P.\} and Kovalevsky, \{Andrei Yu\} and Diver, \{Steven T.\}",

year = "2006",

month = jun,

day = "8",

doi = "10.1021/ol060657a",

language = "English",

volume = "8",

pages = "2511--2514",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "12",

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T1 - Macrocycle ring expansion by double Stevens rearrangement

AU - Ellis-Holder, Keisha K.

AU - Peppers, Brian P.

AU - Kovalevsky, Andrei Yu

AU - Diver, Steven T.

PY - 2006/6/8

Y1 - 2006/6/8

N2 - New benzimidazolidinone cyclophanes were synthesized through a double Stevens rearrangement employed as a ring expansion technique. Para-substituted heterophanes underwent efficient rearrangement. Meta-substituted heterophanes were also prepared. Structure analyses of the new cyclophanes are also provided.

AB - New benzimidazolidinone cyclophanes were synthesized through a double Stevens rearrangement employed as a ring expansion technique. Para-substituted heterophanes underwent efficient rearrangement. Meta-substituted heterophanes were also prepared. Structure analyses of the new cyclophanes are also provided.

UR - https://www.scopus.com/pages/publications/33745581344

U2 - 10.1021/ol060657a

DO - 10.1021/ol060657a

M3 - Article

AN - SCOPUS:33745581344

SN - 1523-7060

VL - 8

SP - 2511

EP - 2514

JO - Organic Letters

JF - Organic Letters

IS - 12

ER -

Macrocycle ring expansion by double Stevens rearrangement

Abstract

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